DC Field | Value | Language |
---|---|---|
dc.contributor.author | Han, S | - |
dc.contributor.author | Singh, NJ | - |
dc.contributor.author | Kang, TY | - |
dc.contributor.author | Choi, KW | - |
dc.contributor.author | Choi, S | - |
dc.contributor.author | Baek, SJ | - |
dc.contributor.author | Kim, KS | - |
dc.contributor.author | Kim, SK | - |
dc.date.accessioned | 2015-06-25T02:55:46Z | - |
dc.date.available | 2015-06-25T02:55:46Z | - |
dc.date.created | 2010-09-22 | - |
dc.date.issued | 2010-01 | - |
dc.identifier.issn | 1463-9076 | - |
dc.identifier.other | 2015-OAK-0000021668 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/11897 | - |
dc.description.abstract | Aromatic pi-pi interaction in the presence of a metal atom has been investigated experimentally and theoretically with the model system of bis(eta(6)-benzene)chromium-benzene cluster (Cr(Bz)(2)-Bz) in which a free solvating benzene is non-covalently attached to the benzene moiety of Cr(Bz)(2). One-photon mass-analyzed threshold ionization (MATI) spectroscopy and first principles calculations are employed to identify the structure of Cr(Bz)(2)-Bz which adopts the parallel-displaced configuration. The decrease in ionization potential for Cr(Bz)(2)-Bz compared with Cr(Bz)(2), resulting from the increase of the cation-pi stabilization energy upon ionization, is consistent with the parallel-displaced structure of the cluster. Theoretical calculations give the detailed cluster structures with associated energetics, thus revealing the nature of pi-pi-metal or pi-pi-cation interactions at the molecular level. | - |
dc.description.statementofresponsibility | open | en_US |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | - |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | Aromatic pi-pi interaction mediated by a metal atom: structure and ionization of the bis(eta(6)-benzene)chromium-benzene cluster | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | en_US |
dc.identifier.doi | 10.1039/B923929D | - |
dc.author.google | Han, S | en_US |
dc.author.google | Singh, NJ | en_US |
dc.author.google | Kim, SK | en_US |
dc.author.google | Kim, KS | en_US |
dc.author.google | Baek, SJ | en_US |
dc.author.google | Choi, S | en_US |
dc.author.google | Choi, KW | en_US |
dc.author.google | Kang, TY | en_US |
dc.relation.volume | 12 | en_US |
dc.relation.issue | 27 | en_US |
dc.relation.startpage | 7648 | en_US |
dc.relation.lastpage | 7653 | en_US |
dc.contributor.id | 10051563 | en_US |
dc.relation.journal | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | en_US |
dc.relation.index | SCI급, SCOPUS 등재논문 | en_US |
dc.relation.sci | SCI | en_US |
dc.collections.name | Journal Papers | en_US |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.12, no.27, pp.7648 - 7653 | - |
dc.identifier.wosid | 000279514500038 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 7653 | - |
dc.citation.number | 27 | - |
dc.citation.startPage | 7648 | - |
dc.citation.title | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | - |
dc.citation.volume | 12 | - |
dc.contributor.affiliatedAuthor | Kim, KS | - |
dc.identifier.scopusid | 2-s2.0-77954327806 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 6 | - |
dc.description.scptc | 6 | * |
dc.date.scptcdate | 2018-10-274 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | BENZENE DIMER | - |
dc.subject.keywordPlus | AB-INITIO | - |
dc.subject.keywordPlus | CATION-PI | - |
dc.subject.keywordPlus | PHOTODISSOCIATION SPECTROSCOPY | - |
dc.subject.keywordPlus | MOLECULAR CLUSTERS | - |
dc.subject.keywordPlus | DOUBLE-RESONANCE | - |
dc.subject.keywordPlus | BASIS-SET | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | SYSTEMS | - |
dc.subject.keywordPlus | ENERGY | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Physics, Atomic, Molecular & Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Physics | - |
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