Nature of anion-templated pi(+)-pi(+) interactions
SCIE
SCOPUS
- Title
- Nature of anion-templated pi(+)-pi(+) interactions
- Authors
- Inacrist Geronimo; N.Jiten Singh; Kim, KS
- Date Issued
- 2011-05
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- Interaction between positively charged aromatic groups (pi(+)-pi(+)) is characterized by anti-parallel, displaced-stacked structures in the presence of counteranions. Binding energies of pyridinium, N-methylpyridinium and N-methylimidazolium dimers are much larger than that of benzene-pyridine (pi-pi) and pyridinium-benzene (pi(+)-pi). Stabilization is attributed to attractive electrostatic interaction with significant dispersion contribution.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/11902
- DOI
- 10.1039/C1CP20348G
- ISSN
- 1463-9076
- Article Type
- Article
- Citation
- PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 13, no. 25, page. 11841 - 11845, 2011-05
- Files in This Item:
-
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.