Total Synthesis of the Purported Structure of Branched Resin Glycosides Merremoside G and H2
SCIE
SCOPUS
- Title
- Total Synthesis of the Purported Structure of Branched Resin Glycosides Merremoside G and H2
- Authors
- Lee, Sukhyun; Rhee, Young Ho
- Date Issued
- 2024-01
- Publisher
- American Chemical Society
- Abstract
- The first total synthesis of the purported structure of branched resin glycosides merremoside G and H2 is accomplished. A signature step is represented by the sequential transition-metal-catalyzed coupling of stable trisaccharide homoallylic alcohol and monosaccharide alkoxyallene to afford the pentasaccharide skeleton. This de novo strategy is conducted under mild conditions with no need of preactivation. In addition, it allows for efficient preparation of the target compounds in combination with late-stage functionalization. © 2024 American Chemical Society.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/120699
- DOI
- 10.1021/acs.orglett.3c03808
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- Organic Letters, vol. 26, no. 3, page. 602 - 606, 2024-01
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