DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, Myungho | - |
dc.contributor.author | Lim, Jungae | - |
dc.contributor.author | Kwon, Sunil | - |
dc.contributor.author | Jeong, Kwanyong | - |
dc.contributor.author | Park, Ji Hoon | - |
dc.contributor.author | Byun, Jaewon | - |
dc.contributor.author | Kim, Soo Min | - |
dc.contributor.author | Han, Jeehoon | - |
dc.date.accessioned | 2024-06-19T02:20:07Z | - |
dc.date.available | 2024-06-19T02:20:07Z | - |
dc.date.created | 2024-06-17 | - |
dc.date.issued | 2024-06 | - |
dc.identifier.issn | 0888-5885 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/123605 | - |
dc.description.abstract | Ionic liquids (ILs) have been utilized in a variety of applications owing to their nonflammability, low volatility, and tunable chemical properties. However, removing impurities during the synthesis process is complex and costly. In this work, we introduce a novel and cost-effective method to purify [bmim][BF4], an IL, by inducing phase separation using a halocarbon refrigerant such as chlorodifluoromethane (Rf-22). The technique utilizes a ternary phase diagram consisting of [bmim][BF4], water, and halocarbons to achieve a purity greater than 99% and simplify the purification process. Large-scale process simulations based on experimental data were performed using the ASPEN Plus process simulator. The minimum [bmim][BF4] sales price of the developed process was estimated to be $12,004 per metric ton, making it an economically viable option for [bmim][BF4] production. | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.relation.isPartOf | Industrial & Engineering Chemistry Research | - |
dc.title | Economically Viable Process for Synthesizing and Purifying Ionic Liquids: 1-Butyl-3-methyl Imidazolium Tetrafluoroborate | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.iecr.4c01218 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Industrial & Engineering Chemistry Research, v.63, no.23, pp.10373 - 10379 | - |
dc.identifier.wosid | 001238226800001 | - |
dc.citation.endPage | 10379 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 10373 | - |
dc.citation.title | Industrial & Engineering Chemistry Research | - |
dc.citation.volume | 63 | - |
dc.contributor.affiliatedAuthor | Han, Jeehoon | - |
dc.identifier.scopusid | 2-s2.0-85195291925 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | IMPURITIES | - |
dc.subject.keywordPlus | SOLUBILITY | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
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