DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yum, S | - |
dc.contributor.author | An, TK | - |
dc.contributor.author | Wang, X | - |
dc.contributor.author | Lee, W | - |
dc.contributor.author | Uddin, MA | - |
dc.contributor.author | Kim, YJ | - |
dc.contributor.author | Nguyen, TL | - |
dc.contributor.author | Xu, S | - |
dc.contributor.author | Hwang, S | - |
dc.contributor.author | Park, CE | - |
dc.contributor.author | Woo, HY | - |
dc.date.accessioned | 2016-03-31T07:52:03Z | - |
dc.date.available | 2016-03-31T07:52:03Z | - |
dc.date.created | 2015-02-04 | - |
dc.date.issued | 2014-03-25 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.other | 2014-OAK-0000031088 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/14097 | - |
dc.description.abstract | We report a series of benzotriazole-based semicrystalline pi-conjugated polymers with noncovalent conformational locks for applications in polymer field-effect transistors. The benzotriazole moiety is a versatile electron-deficient building block that offers two chemically functionalizable sites, 2(N) and 5, 6(C) positions,. allowing easy modulation of the solution processability and electronic structures of the resulting polymers. Fluorine or alkoxy substituents were introduced to the benzotriazole unit to enhance the molecular ordering through intra- and intermolecular F center dot center dot center dot S, F center dot center dot center dot H-C, C-F center dot center dot center dot pi(F), or S center dot center dot center dot O attractive interactions. The fluorinated polymer (PTBTz-F) showed remarkably enhanced hole mobility (mu(h) = 1.9 cm(2)/(V.S), on/off ratio = 8 x 10(7)) upon thermal annealing at 305 degrees C, compared to the unsubstituted one (PTBTz) (mu(h) = 7.0 x 10(-3) cm(2)/(V.s), on/off ratio = 3 x 10(6)). Alkoxy unit substitution (PTBTz-OR) also improved the carrier mobility up to 0.019 cm(2)/(V.s) with an on/off ratio of 4 x 10(5). Fluorine or alkoxy substitution induced tight interchain ordering with edge-on orientation, as confirmed by X-ray diffraction measurements. In particular, fluorinated PTBTz-F showed high thermal stability (T-d 453 degrees C) and the remarkable device characteristics with deep frontier orbital levels. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | CHEMISTRY OF MATERIALS | - |
dc.subject | THIN-FILM TRANSISTORS | - |
dc.subject | HIGH-PERFORMANCE | - |
dc.subject | PHOTOVOLTAIC PROPERTIES | - |
dc.subject | SOLAR-CELLS | - |
dc.subject | HOLE MOBILITY | - |
dc.subject | SIDE-CHAINS | - |
dc.subject | COPOLYMER | - |
dc.subject | SEMICONDUCTORS | - |
dc.subject | SELENOPHENE | - |
dc.subject | DESIGN | - |
dc.title | Benzotriazole-Containing Planar Conjugated Polymers with Noncovalent Conformational Locks for Thermally Stable and Efficient Polymer Field-Effect Transistors | - |
dc.type | Article | - |
dc.contributor.college | 화학공학과 | - |
dc.identifier.doi | 10.1021/CM4042346 | - |
dc.author.google | Yum, S | - |
dc.author.google | An, TK | - |
dc.author.google | Wang, X | - |
dc.author.google | Lee, W | - |
dc.author.google | Uddin, MA | - |
dc.author.google | Kim, YJ | - |
dc.author.google | Nguyen, TL | - |
dc.author.google | Xu, S | - |
dc.author.google | Hwang, S | - |
dc.author.google | Park, CE | - |
dc.author.google | Woo, HY | - |
dc.relation.volume | 26 | - |
dc.relation.issue | 6 | - |
dc.relation.startpage | 2147 | - |
dc.relation.lastpage | 2154 | - |
dc.contributor.id | 10104044 | - |
dc.relation.journal | CHEMISTRY OF MATERIALS | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.26, no.6, pp.2147 - 2154 | - |
dc.identifier.wosid | 000333539300021 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 2154 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 2147 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 26 | - |
dc.contributor.affiliatedAuthor | Park, CE | - |
dc.identifier.scopusid | 2-s2.0-84896967926 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 100 | - |
dc.description.scptc | 83 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | PHOTOVOLTAIC PROPERTIES | - |
dc.subject.keywordPlus | HOLE MOBILITY | - |
dc.subject.keywordPlus | SIDE-CHAINS | - |
dc.subject.keywordPlus | COPOLYMER | - |
dc.subject.keywordPlus | SEMICONDUCTORS | - |
dc.subject.keywordPlus | SELENOPHENE | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | CELLS | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
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