Entry to β-Alkoxyacrylates via Gold-Catalyzed Intramolecular Coupling of Alkynoates and Allylic Ethers
SCIE
SCOPUS
- Title
- Entry to β-Alkoxyacrylates via Gold-Catalyzed Intramolecular Coupling of Alkynoates and Allylic Ethers
- Authors
- Park, SR; Kim, C; Kim, DG; Thrimurtulu, N; Yeom, HS; Jun, J; Shin, S; Rhee, YH
- Date Issued
- 2013-03-15
- Publisher
- American Chemical Society
- Abstract
- The first gold-catalyzed Intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted beta-alkoxyacrylates in a highly efficient manner.
- Keywords
- CLAISEN-TYPE REARRANGEMENT; INTRAMOLECULAR CARBOALKOXYLATION; GOLD(I)-CATALYZED SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; ALKYNES; ALKENES; CYCLIZATION; COMPLEXES; LIGAND; CYCLOISOMERIZATION
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/14528
- DOI
- 10.1021/OL4001087
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- Organic Letters, vol. 14, no. 6, page. 1166 - 1169, 2013-03-15
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- There are no files associated with this item.
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