DC Field | Value | Language |
---|---|---|
dc.contributor.author | Faustini, M | - |
dc.contributor.author | Kim, J | - |
dc.contributor.author | Jeong, GY | - |
dc.contributor.author | Kim, JY | - |
dc.contributor.author | Moon, HR | - |
dc.contributor.author | Ahn, WS | - |
dc.contributor.author | Kim, DP | - |
dc.date.accessioned | 2016-03-31T08:13:33Z | - |
dc.date.available | 2016-03-31T08:13:33Z | - |
dc.date.created | 2014-03-06 | - |
dc.date.issued | 2013-10-02 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | 2013-OAK-0000029206 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/14835 | - |
dc.description.abstract | Herein, we report a novel nanoliter droplet-based microfluidic strategy for continuous and ultrafast synthesis of metal organic framework (MOF) crystals and MOF heterostructures. Representative MOF structures, such as HKUST-1, MOF-5, IRMOF-3, and UiO-66, were synthesized within a few minutes via solvotherrnal reactions with substantially faster kinetics in comparison to the conventional batch processes. The approach was successfully extended to the preparation of a demanding Ru3BTC2 structure that requires high-pressure hydrothermal synthesis conditions. Finally, three different types of core shell MOF composites, i.e., Co3BTC2@Ni3BTC2, MOF-5@diCH(3)-MOF-5, and Fe3O4@ZIF-8, were synthesized by exploiting a unique two-step integrated microfluidic synthesis scheme in a continuous-flow mode. The synthesized MOF crystals were characterized by X-ray diffraction, scanning electron microscopy, and BET surface area measurements. In comparison with bare MOF-5, MOF-5@diCH(3)-MOF-5 showed enhanced structural stability in the presence of moisture, and the catalytic performance of Fe3O4@ZIF-8 was examined using Knoevenagel condensation as a probe reaction. The microfluidic strategy allowed continuous fabrication of high-quality MOF crystals and composites exhibiting distinct morphological characteristics in a time-efficient manner and represents a viable alternative to the time-consuming and multistep MOF synthesis processes. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC(USA) | - |
dc.relation.isPartOf | Journal of the American Chemical Society | - |
dc.subject | ROOM-TEMPERATURE | - |
dc.subject | HIGH-CAPACITY | - |
dc.subject | THIN-FILMS | - |
dc.subject | MOF-5 | - |
dc.subject | STORAGE | - |
dc.subject | STABILITY | - |
dc.subject | DESIGN | - |
dc.title | Microfluidic Approach toward Continuous and Ultrafast Synthesis of Metal−Organic Framework Crystals and Hetero Structures in Confined Microdroplets | - |
dc.type | Article | - |
dc.contributor.college | 화학공학과 | - |
dc.identifier.doi | 10.1021/JA4039642 | - |
dc.author.google | Faustini, M | - |
dc.author.google | Kim, J | - |
dc.author.google | Jeong, GY | - |
dc.author.google | Kim, JY | - |
dc.author.google | Moon, HR | - |
dc.author.google | Ahn, WS | - |
dc.author.google | Kim, DP | - |
dc.relation.volume | 135 | - |
dc.relation.issue | 39 | - |
dc.relation.startpage | 14619 | - |
dc.relation.lastpage | 14626 | - |
dc.contributor.id | 10054896 | - |
dc.relation.journal | Journal of the American Chemical Society | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Journal of the American Chemical Society, v.135, no.39, pp.14619 - 14626 | - |
dc.identifier.wosid | 000326300500032 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 14626 | - |
dc.citation.number | 39 | - |
dc.citation.startPage | 14619 | - |
dc.citation.title | Journal of the American Chemical Society | - |
dc.citation.volume | 135 | - |
dc.contributor.affiliatedAuthor | Kim, DP | - |
dc.identifier.scopusid | 2-s2.0-84885148016 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 107 | - |
dc.description.scptc | 89 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | HIGH-CAPACITY | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | MOF-5 | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | DESIGN | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.