Construction of a Square-wave-shaped One-dimensional Polyrotaxane Using a Preorganized L-shaped Pseudorotaxane
SCIE
SCOPUS
- Title
- Construction of a Square-wave-shaped One-dimensional Polyrotaxane Using a Preorganized L-shaped Pseudorotaxane
- Authors
- Park, KM; Roh, SG; Lee, E; Kim, J; Kim, HJ; Lee, JW; Kim, K
- Date Issued
- 2002-04
- Publisher
- Taylor & Francis
- Abstract
- The construction of a square-wave-shaped one-dimensional polyrotaxane using a preorganized L-shaped [3]pseudorotaxane and metal ion is reported. A phenanthroline derivative having two N-(3-pyridylmethyl)-1,4-butanediammonium "arms" was synthesized as a preorganized L-shaped ligand. This L-shaped ligand easily forms a stable [3]pseudorotaxane incorporating cucurbituril (CB[6]). The reaction of the [3]pseudorotaxane with Ni(II) or Zn(II) ion produces a square-wave-shaped one-dimensional-polyrotaxane.
- Keywords
- coordination polymer; cucurbituril; metal ions; polyrotaxane; supramolecular chemistry; RAY CRYSTAL-STRUCTURES; MOLECULAR MACHINES; 2-DIMENSIONAL POLYROTAXANE; COORDINATION POLYMER; TRANSITION-METALS; CUCURBITURIL; CATENANES; ROTAXANES; AMPLIFICATION; NECKLACE
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/15207
- DOI
- 10.1080/10610270290026059
- ISSN
- 1061-0278
- Article Type
- Article
- Citation
- SUPRAMOLECULAR CHEMISTRY, vol. 14, no. 2-3, page. 153 - 158, 2002-04
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- There are no files associated with this item.
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