DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ki Chang Kwon | - |
dc.contributor.author | Kyoung Soon Choi | - |
dc.contributor.author | Buem Joon Kim | - |
dc.contributor.author | Lee, JL | - |
dc.contributor.author | Soo Young Kim | - |
dc.date.accessioned | 2016-03-31T08:47:28Z | - |
dc.date.available | 2016-03-31T08:47:28Z | - |
dc.date.created | 2015-03-05 | - |
dc.date.issued | 2012-12-20 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.other | 2012-OAK-0000026513 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/16056 | - |
dc.description.abstract | A chemical approach was applied to decrease the work function of few-layer graphene. Li2CO3, K2CO3, Rb2CO3, and Cs2CO3 were used as n-doping materials. The sheet resistance of graphene doped with carbonate salt slightly increased from 1100 to 1700-2500 Omega/sq, and the transmittance of doped graphene with 0.1 M alkali metal at 550 nm decreased from 96.7 to 96.1-94% due to the formation of metal particles on the surface of graphene. A higher sheet resistance and lower transmittance were obtained at a higher concentration of alkali metal carbonate. The G peak in the Raman spectra was shifted to a lower wavenumber after alkali metal carbonate doping and the intensity ratio of the carbon double bond to the carbon single bond decreased with doping in the X-ray photoemission spectroscopy spectra, suggesting the charge transfer from metal ions to graphene sheets. Ultraviolet photoemission spectroscopy data showed that the work function of the graphene sheets decreased from 4.25 eV to 3.8, 3.7, 3.5, and 3.4 eV for graphene doped with Li2CO3, K2CO3, Rb2CO3, and Cs2CO3, respectively. This suggested that spontaneous chemical combination occurred between the carbon atoms and alkali metal, thereby decreasing the work function. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ACS Publications | - |
dc.relation.isPartOf | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.subject | CHEMICAL-VAPOR-DEPOSITION | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | TRANSPARENT ELECTRODES | - |
dc.subject | FUNCTION SURFACE | - |
dc.subject | DOPED GRAPHENE | - |
dc.subject | LARGE-AREA | - |
dc.subject | FILMS | - |
dc.subject | CESIUM | - |
dc.subject | CELLS | - |
dc.subject | LAYERS | - |
dc.title | Work-Function Decrease of Graphene Sheet Using Alkali Metal Carbonates | - |
dc.type | Article | - |
dc.contributor.college | 신소재공학과 | - |
dc.identifier.doi | 10.1021/JP3069927 | - |
dc.author.google | Kwon, KC | - |
dc.author.google | Choi, KS | - |
dc.author.google | Kim, BJ | - |
dc.author.google | Lee, JL | - |
dc.author.google | Kim, SY | - |
dc.relation.volume | 116 | - |
dc.relation.issue | 50 | - |
dc.relation.startpage | 26586 | - |
dc.relation.lastpage | 26591 | - |
dc.contributor.id | 10105416 | - |
dc.relation.journal | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY C, v.116, no.50, pp.26586 - 26591 | - |
dc.identifier.wosid | 000312519600054 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 26591 | - |
dc.citation.number | 50 | - |
dc.citation.startPage | 26586 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.volume | 116 | - |
dc.contributor.affiliatedAuthor | Lee, JL | - |
dc.identifier.scopusid | 2-s2.0-84871604460 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 50 | - |
dc.description.scptc | 45 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FUNCTION SURFACE | - |
dc.subject.keywordPlus | DOPED GRAPHENE | - |
dc.subject.keywordPlus | LARGE-AREA | - |
dc.subject.keywordPlus | FILMS | - |
dc.subject.keywordPlus | ELECTRODES | - |
dc.subject.keywordPlus | CESIUM | - |
dc.subject.keywordPlus | LAYERS | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
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