Advanced Oxidation Process Based on the Cr(III)/Cr(VI) Redox Cycle
SCIE
SCOPUS
- Title
- Advanced Oxidation Process Based on the Cr(III)/Cr(VI) Redox Cycle
- Authors
- Bokare, AD; Choi, W
- Date Issued
- 2011-11-01
- Publisher
- AMER CHEMICAL SOC
- Abstract
- Oxidative degradation of aqueous organic pollutants, using 4-chlorophenol (4-CP) as a main model substrate, was achieved with the concurrent H2O2-mediated transformation of Cr(III) to Cr(VI). The Fenton-like oxidation of 4-CP is initiated by the reaction between the aquo-complex of Cr(III) and H2O2, which generates HO center dot along with the stepwise oxidation of Cr(III) to Cr(VI). The Cr(III)/H2O2 system is inactive in acidic condition, but exhibits maximum oxidative capacity at neutral and near-alkaline pH. Since we previously reported that Cr(VI) can also activate H2O2 to efficiently generate HO center dot, the dual role of H2O2 as an oxidant of Cr(III) and a reductant of Cr(VI) can be utilized to establish a redox cycle of Cr(III)-Cr(VI)-Cr(III). As a result, HO center dot can be generated using both Cr(III)/H2O2 and Cr(VI)/H2O2 reactions, either concurrently or sequentially. The formation of HO center dot was confirmed by monitoring the production of p-hydroxybenzoic acid from [benzoic acid + HO center dot] as a probe reaction and by quenching the degradation of 4-CP in the presence of methanol as a HO center dot scavenger. The oxidation rate of 4-CP in the Cr(III)/H2O2 solution was highly influenced by pH, which is ascribed to the hydrolysis of Cr-III(H2O)(n) into Cr-III(H2O)(n-m)(OH)(m) and the subsequent condensation to oligomers. The present study proposes that the Cr(III)/H2O2 combined with Cr(VI)/H2O2 process is a viable advanced oxidation process that operates over a wide pH range using the reusable redox cycle of Cr(III) and Cr(VI).
- Keywords
- HYDROGEN-PEROXIDE; AQUEOUS-SOLUTION; HEXAVALENT CHROMIUM; ORGANIC POLLUTANTS; HYDROXYL RADICALS; HYDROLYTIC DIMER; WATER EXCHANGE; WASTE-WATER; COMPLEXES; CHEMISTRY
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/16916
- DOI
- 10.1021/ES2021704
- ISSN
- 0013-936X
- Article Type
- Article
- Citation
- ENVIRONMENTAL SCIENCE & TECHNOLOGY, vol. 45, no. 21, page. 9332 - 9338, 2011-11-01
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