DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeon, TH | - |
dc.contributor.author | Choi, W | - |
dc.contributor.author | Park, H | - |
dc.date.accessioned | 2016-03-31T09:41:50Z | - |
dc.date.available | 2016-03-31T09:41:50Z | - |
dc.date.created | 2011-05-16 | - |
dc.date.issued | 2011-04-14 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.other | 2011-OAK-0000023514 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/17486 | - |
dc.description.abstract | Nanocrystalline hematite particles (alpha-Fe2O3) were electrodeposited on the TiO2 nanotube (TiNT) arrays that were fabricated via anodization of Ti foils. The short precontact time (1 h) of aqueous ferric ions (Fe3+) on TINT resulted in formation of hematite particles selectively on the mouth surface of TINT (hematite@1 h/TiNT), whereas the long precontact time (24 h) resulted in complete filling of the TINT inside and an even full-covering of the TiNT top surface with the hematite particles (hematite@24 h/TNT). For comparison, hematite particles were also electrodeposited on TiO2-nanoparticulate films obtained via oxidative annealing of Ti foil resulting in hematite fully covered TiO2 nanoparticles (hematite/TiNP). Photoelectrochemical (PEC) study with AM 1.5 light (UV + Vis) indicated that the PEC activity of TINT decreased by ca. 40% and almost completely vanished when hematite covered the full surface of TiNT (hematite@ 24 h/TiNT) and loaded on the mouth surface of TiNT (hematite@ h/TiNT), respectively. The relatively higher PEC activity of hematite@24 h/TiNT was further observed under varying visible light conditions (400 nm < lambda < 500 nm). Hematite/TiNP also has ca. 40%-reduced PEC activity as compared to TiNP under AM 1.5 light, the tendency of which is similar to hematite@24 h/TiNT. Photocatalytic (PC) activities of TNT and hematite/TINT for degradation of aqueous phenol under AM 1.5-light were also compared, which indicates that the PC activity of TiNT vanishes almost completely with hematite@1 h/TiNT, whereas it is recovered at a moderate level with hematite@24 h/TiNT. All of these PEC and PC behaviors of TNT and hematite/TiNT were discussed in terms of hematite-induced charge recombination due to an energy level mismatch between TiO2 and hematite, as well as surface-specific photoactivity of TINT (i.e., mouth surface vs interwall and/or underlying base layer). Various surface analysis techniques (XRD, XPS, TEM, UV-vis diffuse reflectance) were employed to understand the surface states of TiNT and hematite/TINT. Finally, more detailed charge transfer mechanism was proposed. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.subject | SENSITIZED SOLAR-CELLS | - |
dc.subject | TIO2 NANOTUBES | - |
dc.subject | HYDROGEN-PRODUCTION | - |
dc.subject | THIN-FILMS | - |
dc.subject | ENVIRONMENTAL APPLICATIONS | - |
dc.subject | WATER | - |
dc.subject | SUBSTRATE | - |
dc.subject | ELECTRODE | - |
dc.subject | DEGRADATION | - |
dc.subject | ANODIZATION | - |
dc.title | Photoelectrochemical and Photocatalytic Behaviors of Hematite-Decorated Titania Nanotube Arrays: Energy Level Mismatch versus Surface Specific Reactivity | - |
dc.type | Article | - |
dc.contributor.college | 환경공학부 | - |
dc.identifier.doi | 10.1021/JP201215T | - |
dc.author.google | Jeon, TH | - |
dc.author.google | Choi, W | - |
dc.author.google | Park, H | - |
dc.relation.volume | 115 | - |
dc.relation.issue | 14 | - |
dc.relation.startpage | 7134 | - |
dc.relation.lastpage | 7142 | - |
dc.contributor.id | 10105056 | - |
dc.relation.journal | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY C, v.115, no.14, pp.7134 - 7142 | - |
dc.identifier.wosid | 000289215400125 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 7142 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 7134 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.volume | 115 | - |
dc.contributor.affiliatedAuthor | Choi, W | - |
dc.identifier.scopusid | 2-s2.0-79953751829 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 45 | - |
dc.description.scptc | 46 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | SENSITIZED SOLAR-CELLS | - |
dc.subject.keywordPlus | TIO2 NANOTUBES | - |
dc.subject.keywordPlus | HYDROGEN-PRODUCTION | - |
dc.subject.keywordPlus | THIN-FILMS | - |
dc.subject.keywordPlus | ENVIRONMENTAL APPLICATIONS | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | SUBSTRATE | - |
dc.subject.keywordPlus | ELECTRODE | - |
dc.subject.keywordPlus | DEGRADATION | - |
dc.subject.keywordPlus | ANODIZATION | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
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