DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, E | - |
dc.contributor.author | Lee, E | - |
dc.contributor.author | Park, I | - |
dc.contributor.author | Chang, T | - |
dc.date.accessioned | 2016-03-31T12:57:28Z | - |
dc.date.available | 2016-03-31T12:57:28Z | - |
dc.date.created | 2009-03-19 | - |
dc.date.issued | 2002-01 | - |
dc.identifier.issn | 0032-3896 | - |
dc.identifier.other | 2003-OAK-0000003059 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/18785 | - |
dc.description.abstract | A polar polydimethylsiloxane terminator was prepared and reacted with living copolymer anion of styrene and butadiene, to synthesize end-functionalized styrene-butadiene rubber (SBR). As a polar functional terminator, poly(ethylene glycol)-poly(dimethylsiloxane) block copolymer (PEG-PDMS) containing a chlorosilyl moiety at one chain end (1) was synthesized by two-step hydrosilylation. End capping of poly(styrene-butadiene) living anion with PEG-PDMS terminator (1) afforded polymers with polar poly (di methyl siloxane) end groups. PEG-PDMS terminated SBR, SBR-1, showed higher interaction with silica particles by microscophy and chromatography. Dynamic-mechanical analysis on silica composites of SBR-1 strongly supports the assumption that the PEG-PDMS end groups behave as polar functional groups, showing increase of the glass transition temperature (T-g) and storage modulus in the composite of SBR-1 with silica particles. The SBR-1/silica composite showed lower tan delta at 60degreesC and higher tan (5 at 0degreesC as compared to SBR-Sn/silica composite. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | SOC POLYMER SCIENCE JAPAN | - |
dc.relation.isPartOf | POLYMER JOURNAL | - |
dc.subject | styrene-butadiene rubber | - |
dc.subject | end-functionalization | - |
dc.subject | poly(dimethylsiloxane) terminator | - |
dc.subject | silica particles | - |
dc.subject | dynamic-mechanical analysis | - |
dc.subject | LIVING ANIONIC-POLYMERIZATION | - |
dc.subject | POLYMERS | - |
dc.subject | ADSORPTION | - |
dc.subject | DERIVATIVES | - |
dc.subject | SILICA | - |
dc.title | End functionalization of styrene-butadiene rubber with poly(ethylene glycol)-poly(dimethylsiloxane) terminator | - |
dc.type | Article | - |
dc.contributor.college | BK분자과학사업단 | - |
dc.identifier.doi | 10.1295/polymj.34.674 | - |
dc.author.google | Kim, E | - |
dc.author.google | Lee, E | - |
dc.author.google | Park, I | - |
dc.author.google | Chang, T | - |
dc.relation.volume | 34 | - |
dc.relation.issue | 9 | - |
dc.relation.startpage | 674 | - |
dc.relation.lastpage | 681 | - |
dc.contributor.id | 10052407 | - |
dc.relation.journal | POLYMER JOURNAL | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | POLYMER JOURNAL, v.34, no.9, pp.674 - 681 | - |
dc.identifier.wosid | 000179765200004 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 681 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 674 | - |
dc.citation.title | POLYMER JOURNAL | - |
dc.citation.volume | 34 | - |
dc.contributor.affiliatedAuthor | Chang, T | - |
dc.identifier.scopusid | 2-s2.0-0036907196 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 4 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | LIVING ANIONIC-POLYMERIZATION | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | SILICA | - |
dc.subject.keywordAuthor | styrene-butadiene rubber | - |
dc.subject.keywordAuthor | end-functionalization | - |
dc.subject.keywordAuthor | poly(dimethylsiloxane) terminator | - |
dc.subject.keywordAuthor | silica particles | - |
dc.subject.keywordAuthor | dynamic-mechanical analysis | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
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