Practical ruthenium/lipase-catalyzed asymmetric transformations of ketones and enol acetates to chiral acetates
SCIE
SCOPUS
- Title
- Practical ruthenium/lipase-catalyzed asymmetric transformations of ketones and enol acetates to chiral acetates
- Authors
- Jung, HM; Koh, JH; Kim, MJ; Park, J
- Date Issued
- 2000-08-10
- Publisher
- AMER CHEMICAL SOC
- Abstract
- [GRAPHICS] Ketones were asymmetrically transformed to chiral acetates by one-pot processes using a lipase and an achiral ruthenium complex under 1 atm of hydrogen gas in ethyl acetate. Molecular hydrogen was also effective for the transformation of enol acetates to chiral acetates without additional acyl donors with the same catalyst system.
- Keywords
- DYNAMIC KINETIC RESOLUTION; SECONDARY ALCOHOLS; ENZYMATIC RESOLUTION; RACEMIZATION; PALLADIUM; COMPLEXES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/19899
- DOI
- 10.1021/O|006169Z
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 2, no. 16, page. 2487 - 2490, 2000-08-10
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- There are no files associated with this item.
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