Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts
SCIE
SCOPUS
- Title
- Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts
- Authors
- Lee, D; Huh, EA; Kim, MJ; Jung, HM; Koh, JH; Park, J
- Date Issued
- 2000-07-27
- Publisher
- AMER CHEMICAL SOC
- Abstract
- [GRAPHICS] An enzyme-metal combo reaction has been developed for the dynamic kinetic resolution of allylic alcohols in which racemic substrates are transformed by a lipase and a ruthenium complex in the presence of an acyl donor to allylic acetates of high optical purity in over 80% yield.
- Keywords
- ENZYMATIC RESOLUTION; SECONDARY ALCOHOLS; RACEMIZATION; PALLADIUM; ISOMERIZATION; KETONES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/19916
- DOI
- 10.1021/OL006159Y
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 2, no. 15, page. 2377 - 2379, 2000-07-27
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- There are no files associated with this item.
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