Concerted catalytic reactions for conversion of ketones or enol acetates to chiral acetates
SCIE
SCOPUS
- Title
- Concerted catalytic reactions for conversion of ketones or enol acetates to chiral acetates
- Authors
- Jung, HM; Koh, JH; Kim, MJ; Park, J
- Date Issued
- 2000-02-10
- Publisher
- AMER CHEMICAL SOC
- Abstract
- [GRAPHICS] Enol acetates or ketones asymmetrically transformed to chiral acetates in high yields with high optical purities through multistep reactions catalyzed by a lipase and a ruthenium complex. 2,6-Dimethylheptan-4-ol was chosen as a suitable hydrogen donor, and 4-chlorophenyl acetate was used as an acyl donor for the conversion of ketones.
- Keywords
- DYNAMIC KINETIC RESOLUTION; RUTHENIUM COMPLEXES; SECONDARY ALCOHOLS; ENANTIOSELECTIVE HYDROGENATION; ORGANIC-SYNTHESIS; RACEMIZATION; PALLADIUM
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/20117
- DOI
- 10.1021/ol9914043
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 2, no. 3, page. 409 - 411, 2000-02-10
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- There are no files associated with this item.
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