DC Field | Value | Language |
---|---|---|
dc.contributor.author | RYU, S | - |
dc.contributor.author | KIM, J | - |
dc.contributor.author | YEO, H | - |
dc.contributor.author | KIM, K | - |
dc.date.accessioned | 2016-03-31T14:31:46Z | - |
dc.date.available | 2016-03-31T14:31:46Z | - |
dc.date.created | 2009-03-20 | - |
dc.date.issued | 1995-01-15 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.other | 1995-OAK-0000009087 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/21824 | - |
dc.description.abstract | The first organometallic hafnium(IV) porphyrin complex Hf(TPP)(Me)(2) (TPP = 5,10,15,20-tetraphenylporphyrinate) was synthesized and characterized. The H-1 NMR spectrum of the complex suggested that the methyl groups are cis to each other. An attempt to crystallize the complex yielded the trioxygen-bridged dimer complex [Hf(TPP)](2)(mu-O)(mu-OH)(2) which was presumably formed by hydrolysis. The structure of the hydrolysis product has been determined by X-ray crystallography. The crystal structure revealed two hydroxo and one oxo groups bridging two hafnium porphyrin moieties. Crystal data for [Hf(TPP)](2)(mu-O)(mu-OH)(2): orthorhombic, space group Fdd2, a=25.476(4), b=39.361(8), c=14.848(2) Angstrom, Z=8; R=0.046 and R(w),=0.049 for 1609 independent reflections with 1>3 sigma(I). | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA LAUSANNE | - |
dc.relation.isPartOf | INORGANICA CHIMICA ACTA | - |
dc.title | SYNTHESIS AND CHARACTERIZATION OF THE FIRST ORGANOMETALLIC HAFNIUM PORPHYRIN COMPLEX HF(TPP)(ME)(2) (TPP=5,10,15,20-TETRAPHENYLPORPHYRINATE) AND CRYSTAL-STRUCTURE OF ITS HYDROLYSIS PRODUCT [HF(TPP)](2)(MU-O)(MU-OH)(2) | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1016/0020-1693(94)04161-N | - |
dc.author.google | RYU, S | - |
dc.author.google | KIM, J | - |
dc.author.google | YEO, H | - |
dc.author.google | KIM, K | - |
dc.relation.volume | 228 | - |
dc.relation.issue | 2 | - |
dc.relation.startpage | 233 | - |
dc.relation.lastpage | 236 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | INORGANICA CHIMICA ACTA | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | INORGANICA CHIMICA ACTA, v.228, no.2, pp.233 - 236 | - |
dc.identifier.wosid | A1995QM62400025 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 236 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 233 | - |
dc.citation.title | INORGANICA CHIMICA ACTA | - |
dc.citation.volume | 228 | - |
dc.contributor.affiliatedAuthor | KIM, K | - |
dc.identifier.scopusid | 2-s2.0-0001284830 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 13 | - |
dc.type.docType | Note | - |
dc.subject.keywordPlus | TRANSITION-METAL PORPHYRINS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordAuthor | CRYSTAL STRUCTURES | - |
dc.subject.keywordAuthor | HYDROLYSIS | - |
dc.subject.keywordAuthor | HAFNIUM COMPLEXES | - |
dc.subject.keywordAuthor | PORPHYRIN COMPLEXES | - |
dc.subject.keywordAuthor | ORGANOMETALLIC COMPLEXES | - |
dc.subject.keywordAuthor | TRIOXYGEN-BRIDGED DIMER | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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