DC Field | Value | Language |
---|---|---|
dc.contributor.author | KANG, SG | - |
dc.contributor.author | KIM, MS | - |
dc.contributor.author | CHOI, JS | - |
dc.contributor.author | WHANG, D | - |
dc.contributor.author | KIM, K | - |
dc.date.accessioned | 2016-03-31T14:32:54Z | - |
dc.date.available | 2016-03-31T14:32:54Z | - |
dc.date.created | 2009-03-20 | - |
dc.date.issued | 1995-02 | - |
dc.identifier.issn | 0300-9246 | - |
dc.identifier.other | 1995-OAK-0000009053 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/21847 | - |
dc.description.abstract | The one-step reaction of 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7.12)] docosane (L(1)) with 2-bromoethanol produced the macrocycle 2,13-bis(2-hydroxyethyl)-5,16-dimethyl-2,6,13,17-tetra-azatricyclo[16 .4.0.0(7.12)]docosane (L(2)) in which two 2-hydroxyethyl groups are appended. The nickel(II) and copper(II) complexes of L(2) have been prepared and characterized. The crystal structure of [NiL(2)][ClO4](2) shows that the complex is exactly centrosymmetric and the metal centre has a slightly distorted octahedral geometry with two oxygen atoms of the pendant arms at the axial positions. However. spectra and redox potentials of [CuL(2)][ClO4](2) indicate that the complex has a planar geometry without co-ordination of the pendant arms. The macrocycle L(2) reacts more slowly with copper(rr) ion than does L(1) and the resulting complex dissociates very slowly even at low pH. Crystal data for [NIL(2)][ClO4](2): monoclinic. space group P21(/)n, a = 9.128(2), b = 18.141(3), c = 9.256(2) Angstrom, beta = 101.69(1)degrees, Z = 2, R = 0.057 and R' = 0.060 for 1993 independent reflections with I > 3 sigma(I). | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | - |
dc.subject | LANTHANIDE COMPOUNDS | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | CYCLAM LIGANDS | - |
dc.subject | ACID | - |
dc.subject | 1,4,7,10-TETRAKIS(2-HYDROXYETHYL)-1,4,7,10-TETRAAZACYCLODODECANE | - |
dc.subject | 1,4,8,11-TETRAAZACYCLOTETRADECANE | - |
dc.subject | SUBSTITUENTS | - |
dc.subject | COORDINATION | - |
dc.subject | DERIVATIVES | - |
dc.subject | CHEMISTRY | - |
dc.title | SYNTHESIS AND CHARACTERIZATION OF A DI-N-HYDROXYETHYLATED TETRAAZA MACROCYCLE AND ITS NICKEL(II) AND COPPER(II) COMPLEXES - CRYSTAL-STRUCTURE OF THE NICKEL(II) COMPLEX | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1039/dt9950000363 | - |
dc.author.google | KANG, SG | - |
dc.author.google | KIM, MS | - |
dc.author.google | CHOI, JS | - |
dc.author.google | WHANG, D | - |
dc.author.google | KIM, K | - |
dc.relation.issue | 3 | - |
dc.relation.startpage | 363 | - |
dc.relation.lastpage | 366 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, no.3, pp.363 - 366 | - |
dc.identifier.wosid | A1995QF78600007 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 366 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 363 | - |
dc.citation.title | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | - |
dc.contributor.affiliatedAuthor | KIM, K | - |
dc.identifier.scopusid | 2-s2.0-37049076258 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 60 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | LANTHANIDE COMPOUNDS | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | CYCLAM LIGANDS | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | 1,4,7,10-TETRAKIS(2-HYDROXYETHYL)-1,4,7,10-TETRAAZACYCLODODECANE | - |
dc.subject.keywordPlus | 1,4,8,11-TETRAAZACYCLOTETRADECANE | - |
dc.subject.keywordPlus | SUBSTITUENTS | - |
dc.subject.keywordPlus | COORDINATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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