SYNTHESIS, REACTIVITY, AND MOLECULAR-STRUCTURE OF [(N(CH2CH2O)3SI-C6H5)W(CO)3]
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- Title
- SYNTHESIS, REACTIVITY, AND MOLECULAR-STRUCTURE OF [(N(CH2CH2O)3SI-C6H5)W(CO)3]
- Authors
- CHUNG, YK; KIM, KM; LEE, JS; WHANG, DM
- Date Issued
- 1993-02-23
- Publisher
- ELSEVIER SCIENCE SA LAUSANNE
- Abstract
- Reaction of phenylsilatrane with W(CO)6 gives the compound [C6H5Si(OCH2CH2)3N]W(CO)3 (1) in high yield. Compound 1 has been characterized by elemental analysis, IR, H-1 NMR, and X-ray diffraction methods. Compound 1 crystallizes in the orthorhombic space group Pbca, with a = 22.258(5) angstrom, b = 12.237(1) angstrom, c = 12.313(3) angstrom, and Z = 8. Metallation of 1 by n-butyllithium in THF and subsequent treatment of the lithium derivatives with electrophile have been performed.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/22107
- DOI
- 10.1016/0022-328X(93)80185-E
- ISSN
- 0022-328X
- Article Type
- Article
- Citation
- JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 445, no. 1-2, page. 49 - 54, 1993-02-23
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- There are no files associated with this item.
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