Highly cooperative ion-pair recognition of potassium cyanide using a heteroditopic ferrocene-based crown ether-trifluoroacetylcarboxanilide receptor
SCIE
SCOPUS
- Title
- Highly cooperative ion-pair recognition of potassium cyanide using a heteroditopic ferrocene-based crown ether-trifluoroacetylcarboxanilide receptor
- Authors
- Miyaji, H; Kim, DS; Chang, BY; Park, E; Park, SM; Ahn, KH
- Date Issued
- 2008-01
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- A heteroditopic receptor having crown ether and trifluoroacetylcarboxanilide groups selectively recognizes both potassium and cyanide ions in acetonitrile with an association constant of as high as K-a = 1.9 x 6 10(7) M-1 through a highly cooperative ion-pair interaction, resulting in two orders of magnitude enhancement in the binding affinity.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/22965
- DOI
- 10.1039/B715633B
- ISSN
- 1359-7345
- Article Type
- Article
- Citation
- CHEMICAL COMMUNICATIONS, no. 6, page. 753 - 755, 2008-01
- Files in This Item:
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