DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, D | - |
dc.contributor.author | Yun, YS | - |
dc.contributor.author | Park, JM | - |
dc.date.accessioned | 2016-04-01T01:29:39Z | - |
dc.date.available | 2016-04-01T01:29:39Z | - |
dc.date.created | 2009-08-25 | - |
dc.date.issued | 2008-01-01 | - |
dc.identifier.issn | 0021-9797 | - |
dc.identifier.other | 2008-OAK-0000007333 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/23054 | - |
dc.description.abstract | The reduction of toxic Cr(VI) to the less or nontoxic Cr(III) may be an useful detoxification technique for the treatment of Cr(VI)-contaminated waters. Recently, the protonated biomass of brown seaweed, Ecklonia, was shown to completely reduce Cr(VI) to Cr(III) in the pH range 1-5. The reduction of Cr(VI) to Cr(III) appeared to occur at the surface of the biomass. In this study, abiotic Cr(VI) reduction by the biomass was performed with various contact times, pHs and initial Cr(VI) concentrations, and surface and bulk characteristics of the Cr-laden biomass was then investigated using X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The XPS spectra indicated that the Cr(VI) bound to the biomass was completely reduced to Cr(III) at tested various conditions. XANES and EXAFS spectra of the Cr-laden biomass were very similar to those of Cr(Ill)-acetate, which means that the Cr bound to the biomass during Cr(VI) reduction had an octahedral geometrical arrangement. The bonding distance of the chromium oxygen atoms was approximately 1.97-1.99 angstrom. In conclusion, it was obvious that oxygen containing groups, such as carboxyl and phenolic groups, play a major role in the binding of the Cr(III) resulting from the abiotic reduction of Cr(VI) by the biomass. (c) 2007 Elsevier Inc. All rights reserved. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.relation.isPartOf | JOURNAL OF COLLOID AND INTERFACE SCIENCE | - |
dc.subject | biosorption | - |
dc.subject | hexavalent chromium | - |
dc.subject | Ecklonia | - |
dc.subject | adsorption-coupled reduction | - |
dc.subject | HEXAVALENT CHROMIUM | - |
dc.subject | BROWN SEAWEED | - |
dc.subject | ACTIVATED CARBONS | - |
dc.subject | ECKLONIA BIOMASS | - |
dc.subject | TREATED BIOMASS | - |
dc.subject | REDUCTION | - |
dc.subject | REMOVAL | - |
dc.subject | MECHANISM | - |
dc.subject | TRIVALENT | - |
dc.subject | CHROMATE | - |
dc.title | XAS and XPS studies on chromium-binding groups of biomaterial during Cr(VI) biosorption | - |
dc.type | Article | - |
dc.contributor.college | 화학공학과 | - |
dc.identifier.doi | 10.1016/j.jcis.2007.09.049 | - |
dc.author.google | Park, D | - |
dc.author.google | Yun, YS | - |
dc.author.google | Park, JM | - |
dc.relation.volume | 317 | - |
dc.relation.issue | 1 | - |
dc.relation.startpage | 54 | - |
dc.relation.lastpage | 61 | - |
dc.contributor.id | 10054404 | - |
dc.relation.journal | JOURNAL OF COLLOID AND INTERFACE SCIENCE | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF COLLOID AND INTERFACE SCIENCE, v.317, no.1, pp.54 - 61 | - |
dc.identifier.wosid | 000251283100007 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 61 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 54 | - |
dc.citation.title | JOURNAL OF COLLOID AND INTERFACE SCIENCE | - |
dc.citation.volume | 317 | - |
dc.contributor.affiliatedAuthor | Park, JM | - |
dc.identifier.scopusid | 2-s2.0-36148946037 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 143 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | HEXAVALENT CHROMIUM | - |
dc.subject.keywordPlus | BROWN SEAWEED | - |
dc.subject.keywordPlus | ACTIVATED CARBONS | - |
dc.subject.keywordPlus | ECKLONIA BIOMASS | - |
dc.subject.keywordPlus | TREATED BIOMASS | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | REMOVAL | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | TRIVALENT | - |
dc.subject.keywordPlus | CHROMATE | - |
dc.subject.keywordAuthor | biosorption | - |
dc.subject.keywordAuthor | hexavalent chromium | - |
dc.subject.keywordAuthor | Ecklonia | - |
dc.subject.keywordAuthor | adsorption-coupled reduction | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.