Dynamic switching between single- and double-axial rotaxanes manipulated by charge and bulkiness of axle termini
SCIE
SCOPUS
- Title
- Dynamic switching between single- and double-axial rotaxanes manipulated by charge and bulkiness of axle termini
- Authors
- Yang, C; Ko, YH; Selvapalam, N; Origane, Y; Mori, T; Wada, T; Kim, K; Inoue, Y
- Date Issued
- 2007-11-08
- Publisher
- AMER CHEMICAL SOC
- Abstract
- Twin-axial [3]pseudorotaxanes, in which two multicharged axles simultaneously thread through the V-CD cavity, were formed for the first time in solution. The twin-axial [3]pseudorotaxane was converted exclusively to a CB (6]-stoppered [4]pseudorotaxane by the addition of CB(6] but regenerated from the [4]pseudorotaxane by the addition of spermine, implementing an unprecedented switching of single/twin-axial rotaxanation.
- Keywords
- GAMMA-CYCLODEXTRIN CAVITY; MOLECULAR SHUTTLE; SUPRAMOLECULAR ASSEMBLIES; INTERLOCKED MOLECULES; ALPHA-CYCLODEXTRIN; CUCURBITURIL; MACHINES; 2-ANTHRACENECARBOXYLATE; PHOTOCYCLODIMERIZATION; POLYROTAXANE
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/23088
- DOI
- 10.1021/OL702142J
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 9, no. 23, page. 4789 - 4792, 2007-11-08
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- There are no files associated with this item.
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