Wire-mesh honeycomb catalysts for selective catalytic reduction of NO with NH3
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- Title
- Wire-mesh honeycomb catalysts for selective catalytic reduction of NO with NH3
- Authors
- Yao, J; Choi, JS; Yang, KS; Sun, DZ; Chung, JS
- Date Issued
- 2006-11
- Publisher
- KOREAN INST CHEM ENGINEERS
- Abstract
- Both flat and corrugated wire mesh sheets were coated with aluminum powder by using electrophoretic deposition (EPD) method. Controlled thermal sintering of coated samples yielded uniform porous aluminum layer with a thickness of 100 mu m that was attached firmly on the wire meshes. Subsequent controlled calcination formed a finite thickness of Al2O3 layer on the outer surface of each deposited aluminum particles, which resulted in the formation of Al2O3/Al double-layered composite particles that were attached firmly on the wire surface to form a certain thickness of porous layer. A rectangular-shaped wire-mesh honeycomb (YVMH) module with triangular-shaped channels was manufactured by packing alternately the flat sheet and corrugated sheet of the Al2O3/Al-coated wire meshes. This WMH was further coated With V2O5-MoO3-WO3 catalyst by wash-coating method to be applied for the selective catalytic reduction (SCR) of NO with NH3. With an optimized catalyst loading of 16 wt%, WMH catalyst module shows more than 90% NO conversion at 240 degrees C and almost complete NO conversion at temperatures higher than 300 degrees C at GHSV 5,000 h(-1). When compared with conventional ceramic honeycomb catalyst, WMH catalyst gives NO conversion higher by 20% due to reduced mass transfer resistance by the existence of three dimensional opening holes in WMH.
- Keywords
- EPD method; Al/Al2O3 layer; WMH; SCR of NO; NH3; V2O5-WO3/TiO2; catalyst; VANADIA-TITANIA CATALYSTS; NITRIC-OXIDE; V2O5/TIO2 CATALYST; AMMONIA; SILICA; PERFORMANCE; OXIDATION; GELS
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/23672
- DOI
- 10.1007/s11814-006-0004-4
- ISSN
- 0256-1115
- Article Type
- Article
- Citation
- KOREAN JOURNAL OF CHEMICAL ENGINEERING, vol. 23, no. 6, page. 888 - 895, 2006-11
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