Pure and modified TiO2 photocatalysts and their environmental applications

Abstract

Semiconductor photocatalysis is a process that harnesses light energy in chemical conversions. In particular, its applications to environmental remediation have been intensively investigated. The characteristics of TiO2, the most popular photocatalyst, is briefly described and selected studies on the degradation/conversion of various recalcitrant pollutants using pure and modified TiO2 photocatalysts, which were carried out in this group, are reviewed. Photocatalytic reactions are multi-phasic and take place at interfaces of not only water/TiO2 and air/TiO2 but also solid/TiO2. Examples of photocatalytic reactions of various organic and inorganic substrates that are converted through the photocatalytic oxidation or reduction are introduced. TiO2 has been modified in various ways to improve its photocatalytic activity. Surface modifications of TiO2 that include surface platinization, surface fluorination, and surface charge alteration are discussed and their applications to pollutants degradation are also described in detail.