DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gao, Y | - |
dc.contributor.author | Wada, T | - |
dc.contributor.author | Yang, K | - |
dc.contributor.author | Kim, K | - |
dc.contributor.author | Inoue, Y | - |
dc.date.accessioned | 2016-04-01T02:08:19Z | - |
dc.date.available | 2016-04-01T02:08:19Z | - |
dc.date.created | 2009-02-28 | - |
dc.date.issued | 2005-01 | - |
dc.identifier.issn | 0899-0042 | - |
dc.identifier.other | 2005-OAK-0000005241 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/24504 | - |
dc.description.abstract | By using homochiral mesoporous POST-1 (Scheme 1) as an inherently chiral sensitizing host, supramolecular enantiodifferentiating photoisomerizations of (Z)-cyclooctene (1Z) were performed for the first time to examine the sensitizing ability of the chiral nanopores, walls of which are decorated with pyridine chromophore. The homochiral nanopores of POST-1 crystals were demonstrated to function as an effective chiral-sensitizing cavity to give the optically active (E)-isomer 1E in up to 5% enantiomeric excess (ee), thus expanding the scope of porous material-mediated chirogenesis to both ground and excited electronic states. Chirality 17:S19-S23, 2005. (c) 2005 Wiley-Liss, Inc. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | WILEY-LISS | - |
dc.relation.isPartOf | CHIRALITY | - |
dc.subject | asymmetric synthesis | - |
dc.subject | chiral photochemistry | - |
dc.subject | homochiral material | - |
dc.subject | photosensitization | - |
dc.subject | sensitizing host | - |
dc.subject | metal-organic porous materials | - |
dc.subject | ASYMMETRIC PHOTOCHEMISTRY | - |
dc.subject | PRODUCT CHIRALITY | - |
dc.subject | CYCLOOCTENE | - |
dc.subject | ISOMERIZATION | - |
dc.subject | TEMPERATURE | - |
dc.subject | BENZENEPOLYCARBOXYLATES | - |
dc.title | Supramolecular photochirogenesis in sensitizing chiral nanopore: Enantiodifferentiating photoisomerization of (Z)-cyclooctene included and sensitized by POST-1 | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1002/CHIR.20102 | - |
dc.author.google | Gao, Y | - |
dc.author.google | Wada, T | - |
dc.author.google | Yang, K | - |
dc.author.google | Kim, K | - |
dc.author.google | Inoue, Y | - |
dc.relation.volume | 17 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | CHIRALITY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Conference Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | CHIRALITY, v.17, pp.S19 - S23 | - |
dc.identifier.wosid | 000230320200004 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | S23 | - |
dc.citation.startPage | S19 | - |
dc.citation.title | CHIRALITY | - |
dc.citation.volume | 17 | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-21844461547 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 14 | - |
dc.description.scptc | 21 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article; Proceedings Paper | - |
dc.subject.keywordPlus | ASYMMETRIC PHOTOCHEMISTRY | - |
dc.subject.keywordPlus | PRODUCT CHIRALITY | - |
dc.subject.keywordPlus | CYCLOOCTENE | - |
dc.subject.keywordPlus | ISOMERIZATION | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | BENZENEPOLYCARBOXYLATES | - |
dc.subject.keywordAuthor | asymmetric synthesis | - |
dc.subject.keywordAuthor | chiral photochemistry | - |
dc.subject.keywordAuthor | homochiral material | - |
dc.subject.keywordAuthor | photosensitization | - |
dc.subject.keywordAuthor | sensitizing host | - |
dc.subject.keywordAuthor | metal-organic porous materials | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Medicinal | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Analytical | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalWebOfScienceCategory | Pharmacology & Pharmacy | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Pharmacology & Pharmacy | - |
dc.relation.journalResearchArea | Chemistry | - |
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