DC Field | Value | Language |
---|---|---|
dc.contributor.author | Banerjee, M | - |
dc.contributor.author | Das, S | - |
dc.contributor.author | Yoon, M | - |
dc.contributor.author | Choi, HJ | - |
dc.contributor.author | Hyun, MH | - |
dc.contributor.author | Park, SM | - |
dc.contributor.author | Seo, G | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2016-04-01T03:15:57Z | - |
dc.date.available | 2016-04-01T03:15:57Z | - |
dc.date.created | 2010-04-13 | - |
dc.date.issued | 2009-06-10 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | 2009-OAK-0000020415 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/26453 | - |
dc.description.abstract | The postsynthetic modification strategy is adopted to demonstrate for the first time the syntheses of catalytically active chiral MOPMs from a preassambled achiral framework, MIL-101, by attaching L-proline-derived chiral catalytic units to the open metal coordination sites of the host framework. Various characterization techniques (including PXRD, TGA, IR, and N-2 absorption measurements) indicated that the chiral units are successfully incorporated into MIL-101, keeping the parent framework intact. The new chiral MOPMs show remarkable catalytic activities in asymmetric aldol reactions (yield up to 90% and ee up to 80%). It is interesting to note that these heterogeneous catalysts show much higher enantioselectivity than the corresponding chiral catalytic units as homogeneous catalysts. This study demonstrates a simple and efficient route for the generation of catalytically active chiral MOPMs. A variety of chiral catalytic units can be, in principle, incorporated into chemically robust achiral MOPMs with large pores by postmodification and the resulting chiral MOPMs may find useful applications in catalytic asymmetric transformations. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.subject | HETEROGENEOUS ASYMMETRIC CATALYSIS | - |
dc.subject | ALDOL REACTIONS | - |
dc.subject | HYDROGEN STORAGE | - |
dc.title | Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials | - |
dc.type | Article | - |
dc.contributor.college | 첨단재료과학부 | - |
dc.identifier.doi | 10.1021/JA901440G | - |
dc.author.google | Banerjee, M | - |
dc.author.google | Das, S | - |
dc.author.google | Yoon, M | - |
dc.author.google | Choi, HJ | - |
dc.author.google | Hyun, MH | - |
dc.author.google | Park, SM | - |
dc.author.google | Seo, G | - |
dc.author.google | Kim, K | - |
dc.relation.volume | 131 | - |
dc.relation.issue | 22 | - |
dc.relation.startpage | 7524 | - |
dc.relation.lastpage | + | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.22, pp.7524 - + | - |
dc.identifier.wosid | 000267177900023 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | + | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 7524 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 131 | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-67650523201 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 267 | - |
dc.description.scptc | 247 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.