A Stereoselective Access to Cyclic cis-1,2-Amino Alcohols from trans-1,2-Azido Alcohol Precursors
SCIE
SCOPUS
- Title
- A Stereoselective Access to Cyclic cis-1,2-Amino Alcohols from trans-1,2-Azido Alcohol Precursors
- Authors
- Dong-gil Kim; Wook Jeong; Won Jong Lee; Soyeong Kang; Han Kyu Pak; Park, J; Young Ho Rhee
- Date Issued
- 2015-05-04
- Publisher
- Wiley-VCH Verlag GmbH & Co. KGaA
- Abstract
- A unique one-pot synthesis of cyclic cis-1,2-amino alcohols from trans-1,2-azido alcohol precursors was developed. The key step is highlighted by the stereoselective reduction of the cyclic alpha-alkoxy imines, which could be prepared from the corresponding azides by ruthenium catalysis under photolytic conditions. Remarkably, this unprecedented reaction pathway offers a stereodivergent access to structurally diverse cyclic 1,2-amino alcohols.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/26933
- DOI
- 10.1002/ADSC.201500267
- ISSN
- 1615-4150
- Article Type
- Article
- Citation
- Advanced Synthesis & Catalysis, vol. 357, no. 7, page. 1398 - 1404, 2015-05-04
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