DC Field | Value | Language |
---|---|---|
dc.contributor.author | PARK, JW | - |
dc.contributor.author | HENLING, LM | - |
dc.contributor.author | SCHAEFER, WP | - |
dc.contributor.author | GRUBBS, RH | - |
dc.date.accessioned | 2016-04-01T08:25:00Z | - |
dc.date.available | 2016-04-01T08:25:00Z | - |
dc.date.created | 2009-10-07 | - |
dc.date.issued | 1991-01 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.other | 1991-OAK-0000019121 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/27922 | - |
dc.description.abstract | The heteronuclear mu-methylene mu-phenyl complexes Cp2Ti(mu-CH2)[mu-p-(CH3)2NC6H4]Rh(1,5-COD) (3b) (1,5-COD = 1,5-cyclooctadiene) and Cp2Ti(mu-CH2)(mu-o-MeOC6H4)RH((1,5-COD) (3c) were synthesized from Cp2Ti(mu-CH2)(mu-Cl)Rh(1,5-COD) (1) and the appropriate aromatic lithium reagent. The structure of 3b was determined by single-crystal X-ray crystallography. The two metal atoms are bridged by the mu-methylene carbon remaining from 1 and by ipso carbon of the p-(N,N-dimethylamino)phenyl group. Compound 3b crystallizes in the triclinic system, in space group P1 (No. 2), with a = 8.988 (1)-angstrom, b = 10.169 (1) angstrom, c = 13.707 (2) angstrom, alpha- = 102.85 (1)-degrees, beta = 103.47 (1)-degrees, gamma = 101.36 (1)-degrees, V = 1146.2 (2) angstrom-3, and Z = 2. The structure was solved and refined with a final R = 0.0370 by using 3882 independent reflections. Complex 3c was shown to have a similar structure by spectroscopic comparison to 3b. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | ORGANOMETALLICS | - |
dc.title | THE STRUCTURE OF TITANIUM-RHODIUM HETEROBINUCLEAR COMPLEXES WITH MU-PHENYL LIGANDS | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/om00047a045 | - |
dc.author.google | PARK, JW | - |
dc.author.google | HENLING, LM | - |
dc.author.google | SCHAEFER, WP | - |
dc.author.google | GRUBBS, RH | - |
dc.relation.volume | 10 | - |
dc.relation.issue | 1 | - |
dc.relation.startpage | 171 | - |
dc.relation.lastpage | 175 | - |
dc.contributor.id | 10053210 | - |
dc.relation.journal | ORGANOMETALLICS | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.10, no.1, pp.171 - 175 | - |
dc.identifier.wosid | A1991ER63000045 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 175 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 171 | - |
dc.citation.title | ORGANOMETALLICS | - |
dc.citation.volume | 10 | - |
dc.contributor.affiliatedAuthor | PARK, JW | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 30 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | RAY CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | METHYLENE COMPLEXES | - |
dc.subject.keywordPlus | OXIDATIVE ADDITION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | COMPOUND | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | CLUSTER | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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