DC Field | Value | Language |
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dc.contributor.author | Park, T | - |
dc.contributor.author | Zimmerman, SC | - |
dc.date.accessioned | 2016-04-01T08:52:05Z | - |
dc.date.available | 2016-04-01T08:52:05Z | - |
dc.date.created | 2009-09-30 | - |
dc.date.issued | 2006-09-06 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | 2006-OAK-0000016632 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/28943 | - |
dc.description.abstract | A supramolecular network polymer consisting of a pair of immiscible polymers, poly( butyl)methacrylate ( PBMA) and polystyrene ( PS), is described. A urea of guanosine ( 1, UG) and 2,7-diamido1,8-naphthyridine ( 2, DAN), which form an exceptionally strong quadruply hydrogen-bonding complex, are displayed at 1-10 mol % along the main backbone of PBMA and PS, respectively. H-1 NMR studies show heterocomplexation between UG and DAN exclusively. This high-fidelity, high- affinity supramolecular connection of two different polymer coils at the molecular level produces a polymer blend. Blends containing different weight ratios of the polymers and mole percent of the recognition units were characterized by AFM and DSC experiments with no isolated domains observed and a single glass-transition temperature ( T-g). The T-g is tunable by varying the weight ratio of the polymers in the blend. In addition, viscosity measurements, size-exclusion chromatography ( SEC), and dynamic light-scattering ( DLS) studies demonstrate the formation of a supramolecular network structure. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.subject | DYNAMIC LIGHT-SCATTERING | - |
dc.subject | CONTROLLED RADICAL POLYMERIZATION | - |
dc.subject | GLASS-TRANSITION TEMPERATURES | - |
dc.subject | DIBLOCK COPOLYMER BLENDS | - |
dc.subject | SITU FORMED COPOLYMERS | - |
dc.subject | BONDING INTERACTION | - |
dc.subject | THERMOREVERSIBLE GELATION | - |
dc.subject | POLY(ALKYL ACRYLATES) | - |
dc.subject | REVERSIBLE POLYMERS | - |
dc.subject | SURFACE-MORPHOLOGY | - |
dc.title | FORMATION OF A MISCIBLE SUPRAMOLECULAR POLYMER BLEND THROUGH SELF-ASSEMBLY MEDIATED BY A QUADRUPLY HYDROGEN-BONDED HETEROCOMPLEX | - |
dc.type | Article | - |
dc.contributor.college | 화학공학과 | - |
dc.identifier.doi | 10.1021/JA0631854 | - |
dc.author.google | Park, T | - |
dc.author.google | Zimmerman, SC | - |
dc.relation.volume | 128 | - |
dc.relation.issue | 35 | - |
dc.relation.startpage | 11582 | - |
dc.relation.lastpage | 11590 | - |
dc.contributor.id | 10148712 | - |
dc.relation.journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.128, no.35, pp.11582 - 11590 | - |
dc.identifier.wosid | 000240116300052 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 11590 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 11582 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 128 | - |
dc.contributor.affiliatedAuthor | Park, T | - |
dc.identifier.scopusid | 2-s2.0-33748418763 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 180 | - |
dc.description.scptc | 169 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | DYNAMIC LIGHT-SCATTERING | - |
dc.subject.keywordPlus | GLASS-TRANSITION TEMPERATURES | - |
dc.subject.keywordPlus | SITU FORMED COPOLYMERS | - |
dc.subject.keywordPlus | THERMOREVERSIBLE GELATION | - |
dc.subject.keywordPlus | POLY(ALKYL ACRYLATES) | - |
dc.subject.keywordPlus | SURFACE-MORPHOLOGY | - |
dc.subject.keywordPlus | HETEROCYCLIC UREAS | - |
dc.subject.keywordPlus | MISCIBILITY | - |
dc.subject.keywordPlus | BLOCK | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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