DC Field | Value | Language |
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dc.date.accessioned | 2016-04-01T08:54:28Z | - |
dc.date.available | 2016-04-01T08:54:28Z | - |
dc.date.issued | 2009-01 | - |
dc.identifier.citation | INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS | - |
dc.identifier.citation | v.58 | - |
dc.identifier.citation | no.1 | - |
dc.identifier.citation | pp.61-76 | - |
dc.identifier.issn | 0091-4037 | - |
dc.identifier.other | 2009-OAK-0000016492 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/29030 | - |
dc.description.abstract | The application of multi-site phase transfer catalyst (denoted herein as QX2) with water-soluble initiator for the radical polymerization of ethyl methacrylate (EMA) was explored. The radical polymerization of water-insoluble vinyl monomer (EMA), with water - soluble initiator (potassium peroxydisulphate PDS) and a multi-site phase transfer catalyst (1,4-bis tributyl methyl ammonium) benzene dichloride TBMABDC) were carried out in a water/cyclohexane two-phase system at constant temperature 601C under nitrogen circumstances. The rate of polymerization (Rp) was determined as a function of various reaction parameters such as the concentration of monomer, initiator, catalyst and variation of the aqueous phase and organic solvents and temperature. Based on the experimental results, a suitable kinetic scheme and mechanism has been proposed for the polymerization reaction. | - |
dc.description.statementofresponsibility | X | - |
dc.publisher | TAYLOR & FRANCIS AS | - |
dc.subject | kinetics | - |
dc.subject | multi-site phase transfer catalyst | - |
dc.subject | radical polymerization | - |
dc.subject | rate polymerization | - |
dc.subject | INTERFACIAL-CATALYSIS | - |
dc.subject | POTASSIUM PEROXYDISULFATE | - |
dc.subject | ACRYLONITRILE | - |
dc.subject | INITIATOR | - |
dc.title | Kinetics and Mechanism of Multi-site Phase Transfer Catalyzed Radical Polymerization of Ethyl Methacrylate | - |
dc.type | Article | - |
dc.identifier.doi | 10.1080/009140308024 | - |
dc.relation.volume | 58 | - |
dc.relation.issue | 1 | - |
dc.relation.startpage | 61 | - |
dc.relation.lastpage | 76 | - |
dc.publisher.location | NO | - |
dc.relation.journal | INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCIE | - |
dc.collections.name | Journal Papers | - |
dc.type.docType | Article | - |
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