DC Field | Value | Language |
---|---|---|
dc.contributor.author | Singh, AK | - |
dc.contributor.author | Jang, S | - |
dc.contributor.author | Kim, JY | - |
dc.contributor.author | Sharma, S | - |
dc.contributor.author | Basavaraju, KC | - |
dc.contributor.author | Kim, MG | - |
dc.contributor.author | Kim, KR | - |
dc.contributor.author | Lee, JS | - |
dc.contributor.author | Lee, HH | - |
dc.contributor.author | Kim, DP | - |
dc.date.accessioned | 2017-07-19T12:26:13Z | - |
dc.date.available | 2017-07-19T12:26:13Z | - |
dc.date.created | 2016-02-26 | - |
dc.date.issued | 2015-11 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/35816 | - |
dc.description.abstract | Generation of hydrogen from renewable sources and its safe utilization for efficient one-pot upgrading of renewable biofuels are a challenge. Bimetallic PdAg catalyst supported on Fe3O4/nitrogen-doped reduced graphene oxide (N-rGO) were synthesized for hydrogen generation from formic acid with high TOF (497 h(-1) at 50 degrees C), and the hydrogen was subsequently utilized in situ for selective defunctionalization of lignin-derived chemicals with preserved aromatic nature at ambient pressure. Hydrodeoxygenation of aromatic aldehydes and ketones gave excellent yields (99% at 130 degrees C) with no use of additives. Furthermore, hydrogenolysis of beta-O-4 and alpha-O-4 C-O model compounds produced only two products with high selectivity at 120 degrees C, which is an efficient and versatile one-pot platform for valorization of lignin biomass. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | ACS CATALYSIS | - |
dc.title | One-Pot Defunctionalization of Lignin-Derived Compounds by Dual-Functional Pd50Ag50/Fe3O4/N-rGO Catalyst | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ACSCATAL.5B01319 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ACS CATALYSIS, v.5, no.11, pp.6964 - 6972 | - |
dc.identifier.wosid | 000364441300089 | - |
dc.date.tcdate | 2019-03-01 | - |
dc.citation.endPage | 6972 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 6964 | - |
dc.citation.title | ACS CATALYSIS | - |
dc.citation.volume | 5 | - |
dc.contributor.affiliatedAuthor | Jang, S | - |
dc.contributor.affiliatedAuthor | Kim, MG | - |
dc.contributor.affiliatedAuthor | Kim, DP | - |
dc.identifier.scopusid | 2-s2.0-84946722752 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 19 | - |
dc.description.scptc | 10 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FORMIC-ACID DECOMPOSITION | - |
dc.subject.keywordPlus | PALLADIUM NANOPARTICLES | - |
dc.subject.keywordPlus | SYNERGISTIC CATALYSIS | - |
dc.subject.keywordPlus | SELECTIVE OXIDATION | - |
dc.subject.keywordPlus | ORGANOSOLV LIGNIN | - |
dc.subject.keywordPlus | HYDROGEN-STORAGE | - |
dc.subject.keywordPlus | BIOFUEL UPGRADE | - |
dc.subject.keywordPlus | AQUEOUS-PHASE | - |
dc.subject.keywordPlus | HYDRODEOXYGENATION | - |
dc.subject.keywordPlus | DEHYDROGENATION | - |
dc.subject.keywordAuthor | formic acid | - |
dc.subject.keywordAuthor | bimetallic catalyst | - |
dc.subject.keywordAuthor | magnetically separable | - |
dc.subject.keywordAuthor | N-doped reduced graphene oxide | - |
dc.subject.keywordAuthor | selective defunctionalization | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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