DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, H | - |
dc.contributor.author | Lee, HJ | - |
dc.contributor.author | Kim, DP | - |
dc.date.accessioned | 2017-07-19T12:32:19Z | - |
dc.date.available | 2017-07-19T12:32:19Z | - |
dc.date.created | 2016-02-26 | - |
dc.date.issued | 2016-01-22 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/35995 | - |
dc.description.abstract | Cycloparaphenylene (CPP) has been recognized as an attractive template for the bottom-up synthesis of carbon nanotubes with uniform diameter, and is important for the chemistry of graphitic as well as ring-shaped macromolecules. However, the reported routes from halogenated benzenes have suffered from low yields even under time-and labor-consuming multistep conditions. Herein we report a flow-assisted synthesis of [10]CPP in four steps under mild conditions. For the synthesis, a selective nucleophilic addition of the unprotected diketone without the double-added byproduct was achieved within 3 s in high yield. Subsequently, the obtained compound was reacted with dilithiated benzene at 25 degrees C to form a U-shaped precursor for CPP in a separate microreactor, which was finally dimerized and aromatized to obtain [10]CPP by a two-step in-flask reaction. Precise control of time and flow facilitated by the flow-assisted system enabled the development of an efficient synthetic route for [10]CPP. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.title | Flow-Assisted Synthesis of [10]Cycloparaphenylene (CPP) via Serial Microreactions under Mild Conditions | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/ANIE.201509748 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.4, pp.1422 - 1426 | - |
dc.identifier.wosid | 000369852200035 | - |
dc.date.tcdate | 2019-03-01 | - |
dc.citation.endPage | 1426 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 1422 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 55 | - |
dc.contributor.affiliatedAuthor | Lee, HJ | - |
dc.contributor.affiliatedAuthor | Kim, DP | - |
dc.identifier.scopusid | 2-s2.0-84957429351 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 11 | - |
dc.description.scptc | 8 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | BOTTOM-UP SYNTHESIS | - |
dc.subject.keywordPlus | FLASH CHEMISTRY | - |
dc.subject.keywordPlus | CARBON NANOTUBES | - |
dc.subject.keywordPlus | ACETALIZATION | - |
dc.subject.keywordPlus | TRANSISTORS | - |
dc.subject.keywordPlus | MACROCYCLES | - |
dc.subject.keywordAuthor | cycloparaphenylene | - |
dc.subject.keywordAuthor | flow chemistry | - |
dc.subject.keywordAuthor | lithiation | - |
dc.subject.keywordAuthor | microfluidics | - |
dc.subject.keywordAuthor | microreactors | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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