DC Field | Value | Language |
---|---|---|
dc.contributor.author | RO, JONG JIN | - |
dc.contributor.author | GO, GUI HAN | - |
dc.contributor.author | L MARCUS WILHELMSSON | - |
dc.contributor.author | KIM, BYEANG HYEAN | - |
dc.date.accessioned | 2018-05-02T06:19:38Z | - |
dc.date.available | 2018-05-02T06:19:38Z | - |
dc.date.created | 2018-01-10 | - |
dc.date.issued | 2018-01 | - |
dc.identifier.issn | 2050-6120 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/40948 | - |
dc.description.abstract | 2'-deoxyfuranouridine derivatives presenting various aryl groups have been synthesized through Cu(I)-catalyzed intramolecular cyclizations. Moreover, corresponding pyrrolo-dC derivatives have been synthesized and both families of compounds thoroughly characterized using UV/vis and fluorescence spectroscopy as well as time-dependent density functional theory calculations. The photophysical characterization, show that our newly synthesized derivatives of the important pyrrolo-dC family have high fluorescence quantum yields (QYs) and brightness values. Pyrrolo-dC derivative, 3a, shows an environment sensitive QY of up to >60% and brightness of almost 3000, in low polarity solvents and excitation and emission maxima between 365-381 nm and 479-510 nm, respectively, in solvents of different polarities. Two other derivatives, 3b and 3c, show high QYs and brightness values of up to 3300 that are fairly insensitive to their microenvironment. These promising photophysical features suggest future applicability as fluorescent nucleobase analogs. | - |
dc.language | English | - |
dc.publisher | IOPscience | - |
dc.relation.isPartOf | Methods and Applications in Fluorescence | - |
dc.title | Fluorescence Properties of 6-Aryl-2´-deoxy-furanouridine and –pyrrolocytidine and their derivatives | - |
dc.type | Article | - |
dc.identifier.doi | 10.1088/2050-6120/aa8e19 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Methods and Applications in Fluorescence, v.6, no.1, pp.015004 | - |
dc.identifier.wosid | 000418415000001 | - |
dc.date.tcdate | 2018-03-23 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 015004 | - |
dc.citation.title | Methods and Applications in Fluorescence | - |
dc.citation.volume | 6 | - |
dc.contributor.affiliatedAuthor | RO, JONG JIN | - |
dc.contributor.affiliatedAuthor | GO, GUI HAN | - |
dc.contributor.affiliatedAuthor | KIM, BYEANG HYEAN | - |
dc.identifier.scopusid | 2-s2.0-85042076849 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | ARTICLE | - |
dc.subject.keywordPlus | DNA-BASE ANALOG | - |
dc.subject.keywordPlus | T7 RNA-POLYMERASE | - |
dc.subject.keywordPlus | NUCLEIC-ACID | - |
dc.subject.keywordPlus | ENZYMATIC INCORPORATION | - |
dc.subject.keywordPlus | MOLECULAR BEACON | - |
dc.subject.keywordPlus | QUANTUM YIELD | - |
dc.subject.keywordPlus | PYRROLO-C | - |
dc.subject.keywordPlus | NUCLEOSIDE | - |
dc.subject.keywordPlus | PROBES | - |
dc.subject.keywordPlus | EMISSION | - |
dc.subject.keywordAuthor | fluorescence | - |
dc.subject.keywordAuthor | base analog | - |
dc.subject.keywordAuthor | DNA | - |
dc.subject.keywordAuthor | nucleic acid | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Analytical | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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