Direct Aryl‐Aryl Coupling without Pre‐Functionalization Enabled by Excessive Oxidation of Two‐Electron Ag(I)/Ag(III) Catalyst
SCIE
SCOPUS
- Title
- Direct Aryl‐Aryl Coupling without Pre‐Functionalization Enabled by Excessive Oxidation of Two‐Electron Ag(I)/Ag(III) Catalyst
- Authors
- Singh, Ajay K.; Kim, Min-Gyu; Lee, Hyune-Jea; Singh, Rakhi; CHO, SEUNG HWAN; KIM, DONG PYO
- Date Issued
- 2018-05
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- Reported herein is a catalytic platform for formation of unsymmetrical biaryls by the coupling between inert Csp2−CH3 and Csp2−H via a tandem catalytic strategy. The platform utilizes traditional AgNO3 catalyst and excess amount of K2S2O8 oxidant. The excessive oxidant present converts the traditional one‐electron Ag(I)/Ag(II) chemistry to two‐electron Ag(I)/Ag(III) one, enabling one‐pot synthesis of aryl‐aryl scaffolds by using unactivated cheap commodity chemicals.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/50099
- DOI
- 10.1002/adsc.201800213
- ISSN
- 1615-4150
- Article Type
- Article
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, vol. 360, no. 10, page. 2032 - 2042, 2018-05
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