Comparative resin kinetics using in situ fluorescence measurements
SCIE
SCOPUS
- Title
- Comparative resin kinetics using in situ fluorescence measurements
- Authors
- Walsh, DP; Pang, C; Parikh, PB; Kim, YS; Chang, Young-Tae
- Date Issued
- 2002-05
- Publisher
- AMER CHEMICAL SOC
- Abstract
- The aminolysis of a novel activated ester resin was utilized for kinetic study via continuous in situ fluorescence measurements. A variety of resin compositions (polystyrene, JandaJel, ArgoPore, TentaGel, NovaGel, and PEGA) and solvents (dimethylformamide, acetonitrile, tetrahydrofuran, 1,2-dichlorethane, and toluene) were tested to compare their effects on the reaction rate. A linear relationship between the reaction rate and (solvent polarity x swelling of resin) was elucidated for the aminolysis reaction.
- Keywords
- PHASE ORGANIC-SYNTHESIS; POLYSTYRENE RESINS; PEPTIDE-SYNTHESIS; LABELING METHOD; SOLID SUPPORT; BINDING ASSAY; ESTERS; LIBRARIES; VERSATILE; REAGENTS
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/50137
- DOI
- 10.1021/cc010063t
- ISSN
- 1520-4766
- Article Type
- Article
- Citation
- JOURNAL OF COMBINATORIAL CHEMISTRY, vol. 4, no. 3, page. 204 - 208, 2002-05
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- There are no files associated with this item.
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