Reversible photoreduction of Cu(II)-coumarin metal-organic polyhedra
SCIE
SCOPUS
- Title
- Reversible photoreduction of Cu(II)-coumarin metal-organic polyhedra
- Authors
- Bae, Jaeyeon; Baek, Kangkyun; Yuan, Daqiang; Kim, Wooram; Kim, Kimoon; Zhou, Hong-Cai; Park, Jinhee
- Date Issued
- 2017-08
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- We report a new approach for photoinduced reduction of Cu2+ that will enrich the structural diversity of coordination complexes and be a valuable contributor to the development of Cu+/Cu-0-based catalysts. To realize controlled Cu2+ reduction, coumarin as a triplet quencher of excited benzophenone was tethered to Cu(II)-metalorganic polyhedra (MOPs). The photoinduced catalytic activity of the coumarin-MOPs was also examined in a Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC).
- Keywords
- CAGES; MOLECULES; CHEMISTRY; NANOCAGES; RELEASE; DRIVEN
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/92054
- DOI
- 10.1039/c7cc04799a
- ISSN
- 1359-7345
- Article Type
- Article
- Citation
- CHEMICAL COMMUNICATIONS, vol. 53, no. 66, page. 9250 - 9253, 2017-08
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- There are no files associated with this item.
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