Structure, Formation and Catalytic Studies of a meso-Palladioporphyrin Intermediate in a Heck Reaction
SCIE
- Title
- Structure, Formation and Catalytic Studies of a meso-Palladioporphyrin Intermediate in a Heck Reaction
- Authors
- Jiang, MY; Shin, JY; Patrick, BO; Dolphin, D
- Date Issued
- 2008-05
- Publisher
- Royal Society of Chemistry
- Abstract
- A meso-palladioporphyrin intermediate was isolated from a Heck reaction between an iodoporphyrin and a non-activated olefin using a Pd(PPh(3))(2)Cl(2)/Et(3)N system; its structure was characterized by NMR, MS and X-ray crystallography. Studies on its formation indicate that the Pd(II) catalyst was reduced in situ by Et(3)N with the assistance of water. The catalytic activity of the intermediate was confirmed by stoichiometric and catalytic reactions using a more reactive olefin, ethyl acrylate.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/92495
- DOI
- 10.1039/b801163j
- ISSN
- 1477-9226
- Article Type
- Article
- Citation
- Dalton Transactions, no. 19, page. 2598 - 2602, 2008-05
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- There are no files associated with this item.
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