DC Field | Value | Language |
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dc.contributor.author | KIM, KYUNG HWAN | - |
dc.contributor.author | Taedong Ok | - |
dc.contributor.author | Kwangyeol Lee | - |
dc.contributor.author | Hee-Seung Lee | - |
dc.contributor.author | Kyu Tae Chang | - |
dc.contributor.author | Hyotcherl Ihee | - |
dc.contributor.author | Jeong-Hun Sohn | - |
dc.date.accessioned | 2018-11-12T01:47:30Z | - |
dc.date.available | 2018-11-12T01:47:30Z | - |
dc.date.created | 2018-10-24 | - |
dc.date.issued | 2010-09-01 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/94160 | - |
dc.description.abstract | Herein we present the long-sought quantitative catalyst-substrate association relationships based on experimentally measured quantitative association preferences of diverse metathesis Mo and Ru catalysts (Mo-1, Schrock Mo; Mo-2, Schrock-Hoveyda Mo; Ru-1, Grubbs first generation Ru; Ru-2, Grubbs second generation Ru; Ru-3:, Grubbs-Hoveyda first generation Ru; and Ru-4, Grubbs-Hoveyda second generation Ru) to their substrates (alkenes, alkynes and allenes), determined directly by a general method based on FRET principle. The determined substrate preferences are proved to be dependent on the molecular identity of the catalyst, exhibiting the preference order of alkyne > alkene > allene for Mo-1 and Mo-2, allene > alkene > alkyne for Ru-1 and Ru-3, and alkyne > allene > alkene for Ru-2 and Ru-4. The results enable us to probe metathesis mechanisms by answering issues in metathesis reactions including the controversial reaction initiation in enyne or allenyne metathesis. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.title | Quantitative Catalyst−Substrate Association Relationships between Metathesis Molybdenum or Ruthenium Carbene Complexes and Their Substrates | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ja104193s | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.34, pp.12027 - 12033 | - |
dc.identifier.wosid | 000281296700050 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 12033 | - |
dc.citation.number | 34 | - |
dc.citation.startPage | 12027 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 132 | - |
dc.contributor.affiliatedAuthor | KIM, KYUNG HWAN | - |
dc.identifier.scopusid | 2-s2.0-77956066502 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 20 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | RING-CLOSING METATHESIS | - |
dc.subject.keywordPlus | IMIDO ALKYLIDENE COMPLEXES | - |
dc.subject.keywordPlus | NOBEL LECTURE 2005 | - |
dc.subject.keywordPlus | ENYNE METATHESIS | - |
dc.subject.keywordPlus | OLEFIN-METATHESIS | - |
dc.subject.keywordPlus | GRUBBS RUTHENIUM | - |
dc.subject.keywordPlus | CROSS-METATHESIS | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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