DC Field | Value | Language |
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dc.contributor.author | He, Zuoli | - |
dc.contributor.author | Kim, Chuhyung | - |
dc.contributor.author | Jeon, Tae Hwa | - |
dc.contributor.author | Choi, Wonyong | - |
dc.date.accessioned | 2019-04-07T15:52:43Z | - |
dc.date.available | 2019-04-07T15:52:43Z | - |
dc.date.created | 2018-10-10 | - |
dc.date.issued | 2018-12 | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/95471 | - |
dc.description.abstract | The increasing need for new materials capable of solar fuel production is central to the development of green energy economy. Utilizing solar energy for hydrogen generation is a great challenge due to inefficient light utilization and fast charge recombination. In this work, disorder-engineered black H-TiO2@BN with Ti-B chemically bonded interfaces was synthesized by employing BN nanosheets as the photocatalyst support. The hybridization of TiO2 with BN and hydrogenated thermal treatment work synergistically to enable the photo catalytic H-2 production without noble metal cocatalysts. The hybrid photocatalyst markedly enhanced light absorption, significantly retarded charge pair recombination, facilitated interfacial electron transfer, and lowered interfacial charge transfer resistance. As a result, the photocatalytic H-2 production activity of H-TiO2@BN that consisted of earth-abundant elements only was comparable to that of Pt-TiO2. The present hybrid engineering for the efficient charge separation and transfer via the formation of the interfacial chemical bonds should provide a useful methodology for designing the new types of hybrid photocatalysts. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.relation.isPartOf | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.title | Hydrogenated heterojunction of boron nitride and titania enables the photocatalytic generation of H-2 in the absence of noble metal catalysts | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.apcatb.2018.06.008 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS B-ENVIRONMENTAL, v.237, pp.772 - 782 | - |
dc.identifier.wosid | 000442973700079 | - |
dc.citation.endPage | 782 | - |
dc.citation.startPage | 772 | - |
dc.citation.title | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.citation.volume | 237 | - |
dc.contributor.affiliatedAuthor | Choi, Wonyong | - |
dc.identifier.scopusid | 2-s2.0-85048702925 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | GRAPHITIC CARBON NITRIDE | - |
dc.subject.keywordPlus | VISIBLE-LIGHT | - |
dc.subject.keywordPlus | CHARGE-TRANSFER | - |
dc.subject.keywordPlus | TIO2 | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | BN | - |
dc.subject.keywordPlus | NANOSHEETS | - |
dc.subject.keywordPlus | EVOLUTION | - |
dc.subject.keywordPlus | COCATALYST | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordAuthor | Photocatalysts | - |
dc.subject.keywordAuthor | BN | - |
dc.subject.keywordAuthor | TiO2 | - |
dc.subject.keywordAuthor | H-2 generation | - |
dc.subject.keywordAuthor | Heterojunction | - |
dc.subject.keywordAuthor | Hydrogenated | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
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