A racemic formal total synthesis of clavukerin A using gold(I)-catalyzed cycloisomerization of 3-methoxy-1,6-enynes as the key strategy
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- Title
- A racemic formal total synthesis of clavukerin A using gold(I)-catalyzed cycloisomerization of 3-methoxy-1,6-enynes as the key strategy
- Authors
- Cheong, JY; Rhee, YH
- Date Issued
- 2011-06-01
- Publisher
- Beilstein institut
- Abstract
- An efficient formal total synthesis of (+/-)-clavukerin A was accomplished via a gold-catalyzed cycloisomerization of a 3-methoxy-1,6-enyne 5 as the key strategy followed by Rh-catalyzed stereoselective hydrogenation of the cycloheptenone 4.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/9817
- DOI
- 10.3762/BJOC.7.84
- ISSN
- 1860-5397
- Article Type
- Article
- Citation
- BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 7, page. 740 - 743, 2011-06-01
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