DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kwon, Hyunchul | - |
dc.contributor.author | Lee, Eunsung | - |
dc.date.accessioned | 2019-07-04T08:31:09Z | - |
dc.date.available | 2019-07-04T08:31:09Z | - |
dc.date.created | 2018-10-10 | - |
dc.date.issued | 2018-09 | - |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/99252 | - |
dc.description.abstract | A study of the coordination chemistry of the hexa(2-pyridyl)benzene (2-HPB) ligand with copper(ii) ions is presented. The 2-HPB ligand featuring six pyridine moieties can bind to a metal center in a number of different ways. Herein, we discuss dicopper(ii) complexes of 2-HPB that vary in coordination geometry. Thus, the four complexes obtained (1, 2, 3, and 4) adopt two different conformations, (A,B)(C,D)-trans (in 1 and 4) and (A,B)(D,E)-trans (in 2 and 3). The structure of the complex strongly depends on the solvent used (water, ethanol, and dimethylformamide (DMF)). In an aqueous solution, the formation of complexes 1 and 2 can be controlled by the choice of crystallization conditions. All the products were characterized by X-ray diffraction. The coordination preference of 2-HPB is evaluated in the context of hydrogen bonding in the solid state. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | CRYSTENGCOMM | - |
dc.title | Coordination preference of hexa(2-pyridyl)benzene with copper(ii) directed by hydrogen bonding | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c8ce00918j | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | CRYSTENGCOMM, v.20, no.35, pp.5233 - 5240 | - |
dc.identifier.wosid | 000444554400018 | - |
dc.citation.endPage | 5240 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 5233 | - |
dc.citation.title | CRYSTENGCOMM | - |
dc.citation.volume | 20 | - |
dc.contributor.affiliatedAuthor | Kwon, Hyunchul | - |
dc.contributor.affiliatedAuthor | Lee, Eunsung | - |
dc.identifier.scopusid | 2-s2.0-85053421677 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | SUPRAMOLECULAR ARCHITECTURES | - |
dc.subject.keywordPlus | LIGAND DESIGN | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | SILVER(I) | - |
dc.subject.keywordPlus | EXCHANGE | - |
dc.subject.keywordPlus | IONS | - |
dc.subject.keywordPlus | SCAFFOLD | - |
dc.subject.keywordPlus | BINDING | - |
dc.subject.keywordPlus | MOTION | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
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