DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hisaaki Tanaka | - |
dc.contributor.author | Ayato Wakamatsu | - |
dc.contributor.author | Masahiro Kondo | - |
dc.contributor.author | Shinya Kawamura | - |
dc.contributor.author | Shin-ichi Kuroda | - |
dc.contributor.author | Yukihiro Shimoi | - |
dc.contributor.author | Won-Tae Park | - |
dc.contributor.author | NOH, YONG YOUNG | - |
dc.contributor.author | Taishi Takenobu | - |
dc.date.accessioned | 2019-11-06T01:30:09Z | - |
dc.date.available | 2019-11-06T01:30:09Z | - |
dc.date.created | 2019-10-31 | - |
dc.date.issued | 2019-08-19 | - |
dc.identifier.issn | 2399-3650 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/99858 | - |
dc.description.abstract | Backbone rigidity of conjugated polymers is suggested to play an essential role in realizing high-mobility transistors through the efficient interconnection of crystalline domains by tie molecules as discussed for the recently-developed donor-acceptor (DA)-type copolymers. However, no studies have directly observed interdomain hopping in these DA copolymers. Here, highly-efficient interdomain charge transport is observed in two typical high-mobility DA copolymers from the microscopic observation of charge carriers using field-induced electron spin resonance (ESR) spectroscopy. The in-plane ESR signal exhibits a clear motional narrowing effect associated with the carrier motion across the boundaries. The activation energy of the interdomain charge motion is as low as that of intradomain motion (~10 meV), both of which are clearly lower than those observed in the conventional semicrystalline polymer. The structural origin of this efficient interdomain electrical connection is the rigid, nearly torsion-free backbone conformation of the tie molecule, as demonstrated from density functional theory calculations. | - |
dc.language | English | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.relation.isPartOf | Communications Physics | - |
dc.title | Microscopic observation of efficient charge transport processes across domain boundaries in donor-acceptor-type conjugated polymers | - |
dc.type | Article | - |
dc.identifier.doi | 10.1038/s42005-019-0196-7 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Communications Physics, v.2, no.1, pp.96 | - |
dc.identifier.wosid | 000481522900001 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 96 | - |
dc.citation.title | Communications Physics | - |
dc.citation.volume | 2 | - |
dc.contributor.affiliatedAuthor | NOH, YONG YOUNG | - |
dc.identifier.scopusid | 2-s2.0-85071152715 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | THIN-FILM TRANSISTORS | - |
dc.subject.keywordPlus | SEMICONDUCTING POLYMERS | - |
dc.subject.keywordPlus | REGIOREGULAR POLY(3-HEXYLTHIOPHENE) | - |
dc.subject.keywordPlus | EFFECT MOBILITY | - |
dc.subject.keywordPlus | LARGE-AREA | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | COPOLYMER | - |
dc.subject.keywordPlus | RESONANCE | - |
dc.subject.keywordPlus | AMBIPOLAR | - |
dc.relation.journalWebOfScienceCategory | Physics, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Physics | - |
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