DC Field | Value | Language |
---|---|---|
dc.contributor.author | Onbattuvelli, VP | - |
dc.contributor.author | Rochefort, WE | - |
dc.contributor.author | Simonsen, J | - |
dc.contributor.author | Park, SJ | - |
dc.contributor.author | German, RM | - |
dc.contributor.author | Atre, SV | - |
dc.date.accessioned | 2016-04-01T02:39:55Z | - |
dc.date.available | 2016-04-01T02:39:55Z | - |
dc.date.created | 2010-11-24 | - |
dc.date.issued | 2010-12-15 | - |
dc.identifier.issn | 0021-8995 | - |
dc.identifier.other | 2010-OAK-0000022049 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/25547 | - |
dc.description.abstract | Effect of heating rate, Pd content, and synthesis method on the thermal stability of the ex situ and in situ Palladium/polycarbonate (Pd/PC) nanocomposites was investigated. TEM images revealed discrete Pd nanoclusters of about 5 and 15 rim sizes for 1 and 2 vol % ex situ nanocomposites, respectively. However, agglomerated Pd nanoclusters were noticed in the in situ samples, irrespective of the Pd content. The ex situ Pd/PC nanocomposites showed high onset temperature (Ti) for thermal degradation of PC than the in situ and pure PC samples. Pd content and heating rates were found to have a positive influence on the Ti and Tin (temperature at the maximum degradation rate occurs) of the Pd/PC nanocomposites. Thermal degradation of the PC was found to follow the first-order kinetics in the Pd/PC nanocomposites. The activation energies associated with the degradation were determined by using the Kissinger method. These activation energies are used to construct the Master decomposition curve (MDC) and weight-time-temperature (alpha-t-T) plots that describe the time-temperature dependence of the PC pyrolysis in the Pd/PC nanocomposites. These constructed alpha-t-T plots were validated with the data from isothermal measurements. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 3602-3611,2010 | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | JOHN WILEY & SONS INC | - |
dc.relation.isPartOf | JOURNAL OF APPLIED POLYMER SCIENCE | - |
dc.subject | palladium/polycarbonate nanocomposites | - |
dc.subject | activation energy | - |
dc.subject | degradation kinetics | - |
dc.subject | GOLD NANOPARTICLES | - |
dc.subject | PALLADIUM | - |
dc.subject | POLYANILINE | - |
dc.subject | DECOMPOSITION | - |
dc.subject | MICROSCOPY | - |
dc.subject | SILVER | - |
dc.subject | CURVE | - |
dc.title | Studies on the Thermal Stability and Degradation Kinetics of Pd/PC Nanocomposites | - |
dc.type | Article | - |
dc.contributor.college | 기계공학과 | - |
dc.identifier.doi | 10.1002/app.32403 | - |
dc.author.google | Onbattuvelli, VP | - |
dc.author.google | Rochefort, WE | - |
dc.author.google | Simonsen, J | - |
dc.author.google | Park, SJ | - |
dc.author.google | German, RM | - |
dc.author.google | Atre, SV | - |
dc.relation.volume | 118 | - |
dc.relation.issue | 6 | - |
dc.relation.startpage | 3602 | - |
dc.relation.lastpage | 3611 | - |
dc.contributor.id | 10060955 | - |
dc.relation.journal | JOURNAL OF APPLIED POLYMER SCIENCE | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF APPLIED POLYMER SCIENCE, v.118, no.6, pp.3602 - 3611 | - |
dc.identifier.wosid | 000282840500059 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 3611 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 3602 | - |
dc.citation.title | JOURNAL OF APPLIED POLYMER SCIENCE | - |
dc.citation.volume | 118 | - |
dc.contributor.affiliatedAuthor | Park, SJ | - |
dc.identifier.scopusid | 2-s2.0-77956913977 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 4 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | GOLD NANOPARTICLES | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | SILVER | - |
dc.subject.keywordPlus | CURVE | - |
dc.subject.keywordAuthor | palladium/polycarbonate nanocomposites | - |
dc.subject.keywordAuthor | activation energy | - |
dc.subject.keywordAuthor | degradation kinetics | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
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