Kinetics and Mechanism of Multi-site Phase Transfer Catalyzed Radical Polymerization of Ethyl Methacrylate
- Title
- Kinetics and Mechanism of Multi-site Phase Transfer Catalyzed Radical Polymerization of Ethyl Methacrylate
- Date Issued
- 2009-01
- Publisher
- TAYLOR & FRANCIS AS
- Abstract
- The application of multi-site phase transfer catalyst (denoted herein as QX2) with water-soluble initiator for the radical polymerization of ethyl methacrylate (EMA) was explored. The radical polymerization of water-insoluble vinyl monomer (EMA), with water - soluble initiator (potassium peroxydisulphate PDS) and a multi-site phase transfer catalyst (1,4-bis tributyl methyl ammonium) benzene dichloride TBMABDC) were carried out in a water/cyclohexane two-phase system at constant temperature 601C under nitrogen circumstances. The rate of polymerization (Rp) was determined as a function of various reaction parameters such as the concentration of monomer, initiator, catalyst and variation of the aqueous phase and organic solvents and temperature. Based on the experimental results, a suitable kinetic scheme and mechanism has been proposed for the polymerization reaction.
- Keywords
- kinetics; multi-site phase transfer catalyst; radical polymerization; rate polymerization; INTERFACIAL-CATALYSIS; POTASSIUM PEROXYDISULFATE; ACRYLONITRILE; INITIATOR
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/29030
- DOI
- 10.1080/009140308024
- ISSN
- 0091-4037
- Article Type
- Article
- Files in This Item:
- There are no files associated with this item.
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